环境科学导刊
環境科學導刊
배경과학도간
ENVIRONMENTAL SCIENCE SURVEY
2014年
1期
99-100
,共2页
重铬酸钾法%化学需氧量%氯离子%干扰%屏蔽
重鉻痠鉀法%化學需氧量%氯離子%榦擾%屏蔽
중락산갑법%화학수양량%록리자%간우%병폐
potassium dichromate method%chemical oxygen demand%chloride ion%interference%shield
探讨了COD为60mg/L的情况下,氯离子对测定值的影响。氯离子浓度在100mg/L时,固态硫酸汞可完全屏蔽其干扰;氯离子浓度在500 mg /L时,液态硫酸汞可完全屏蔽其干扰;绘制COD-氯离子标准曲线,屏蔽氯离子浓度可达2000mg/L,但操作较为繁琐;在水样环境单纯的情况下,用低浓度重铬酸钾法,可忽略氯离子的干扰。
探討瞭COD為60mg/L的情況下,氯離子對測定值的影響。氯離子濃度在100mg/L時,固態硫痠汞可完全屏蔽其榦擾;氯離子濃度在500 mg /L時,液態硫痠汞可完全屏蔽其榦擾;繪製COD-氯離子標準麯線,屏蔽氯離子濃度可達2000mg/L,但操作較為繁瑣;在水樣環境單純的情況下,用低濃度重鉻痠鉀法,可忽略氯離子的榦擾。
탐토료COD위60mg/L적정황하,록리자대측정치적영향。록리자농도재100mg/L시,고태류산홍가완전병폐기간우;록리자농도재500 mg /L시,액태류산홍가완전병폐기간우;회제COD-록리자표준곡선,병폐록리자농도가체2000mg/L,단조작교위번쇄;재수양배경단순적정황하,용저농도중락산갑법,가홀략록리자적간우。
This paper,presented the influence of chloride ion on COD when it was 60mg/L.When chloride ion concentration was about 100mg/L,solid mercury sulfate could be used to screen the interference of chloride ion.It is the same case when chloride ion concentration was about 500mg/L.By drawing the standard curve with COD as the y-coordinate and chloride ion concentration as the x-coordinate,we could see that the maximum chloride ion concentration was about 2000mg/L without interference.But the operation was complicated.The influence of chlo-ride ion might be negligible in water with low COD measuring by 0.025 mol/L potassium dichromate.