蓄电池
蓄電池
축전지
CHINESE LABAT MAN
2014年
1期
38-40
,共3页
铅酸蓄电池%固化%4BS%化成%生正极板%循环寿命
鉛痠蓄電池%固化%4BS%化成%生正極闆%循環壽命
연산축전지%고화%4BS%화성%생정겁판%순배수명
lead-acid battery%curing%tetrabasic lead sulphate%formation%green positive plate%cycle life
采用高温固化和添加4BS晶种的方法,可以使正生极板中形成较多含量4BS的结构,合适的4B S结构对蓄电池的寿命有较好的影响。正生极板要通过化成才能生成有储存电能功能的极板,通过对和膏加入添加剂和采用不同温度固化得到的极板,进行化成前后的结构分析和成分分析,结果认为生成较多含量4B S结构的极板,在化成后形成了小颗粒簇成大颗粒的结构,可能是蓄电池增加寿命的因素。生极板中的4BS含量与化成后α-PbO2没有关系。4BS在化成后的转化没有遗传性,但有继承性。
採用高溫固化和添加4BS晶種的方法,可以使正生極闆中形成較多含量4BS的結構,閤適的4B S結構對蓄電池的壽命有較好的影響。正生極闆要通過化成纔能生成有儲存電能功能的極闆,通過對和膏加入添加劑和採用不同溫度固化得到的極闆,進行化成前後的結構分析和成分分析,結果認為生成較多含量4B S結構的極闆,在化成後形成瞭小顆粒簇成大顆粒的結構,可能是蓄電池增加壽命的因素。生極闆中的4BS含量與化成後α-PbO2沒有關繫。4BS在化成後的轉化沒有遺傳性,但有繼承性。
채용고온고화화첨가4BS정충적방법,가이사정생겁판중형성교다함량4BS적결구,합괄적4B S결구대축전지적수명유교호적영향。정생겁판요통과화성재능생성유저존전능공능적겁판,통과대화고가입첨가제화채용불동온도고화득도적겁판,진행화성전후적결구분석화성분분석,결과인위생성교다함량4B S결구적겁판,재화성후형성료소과립족성대과립적결구,가능시축전지증가수명적인소。생겁판중적4BS함량여화성후α-PbO2몰유관계。4BS재화성후적전화몰유유전성,단유계승성。
By means of curing at high temperature and seeding of 4BS(Tetra-Basic Lead Sulfate) a crystal structure containing more content of 4BS can be achieved in the green positive plate. The appropriate 4BS-structured plate is beneifcial to extending the cycle life of battery, and the green plate can become a plate with the function of energy storage only through formation process. The results from the analysis of both green and formed plates show that the 4BS structure can be converted into an agglomerative structure consisted of many small particles after formation, and this fact may be regarded as a reason for extending the cycle life of battery. Moreover, The content of 4BS in the green plate is inrelevant with that of PbO2 obtained after formation.