环境监测管理与技术
環境鑑測管理與技術
배경감측관리여기술
THE ADMINISTRATION AND TECHNIQUE OF ENVIRONMENTAL MONITORING
2014年
1期
9-13,38
,共6页
石爱军%马俊文%李建军
石愛軍%馬俊文%李建軍
석애군%마준문%리건군
低浓度废气污染物%固定污染源烟气在线监测系统%系统检出限%线性误差%SO2%NO x
低濃度廢氣汙染物%固定汙染源煙氣在線鑑測繫統%繫統檢齣限%線性誤差%SO2%NO x
저농도폐기오염물%고정오염원연기재선감측계통%계통검출한%선성오차%SO2%NO x
Low concentrations pollutants in flue gases%Continuous emission monitoring system (CEMS)%System detection limit%Linearity error%SO2%NO x
通过对7种废气自动监测系统的比较研究和现场测试,提出了非分散红外法、紫外差分法、紫外荧光法、化学发光法等多种 SO2和 NO x 自动监测技术在低浓度范围实现准确定量监测的性能评价方法,定义了 CEMS 的系统检出限及其主要影响因素。建议采用系统检出限、线性误差等关键参数作为低浓度 CEMS 的性能评价方法,提出将全系统多点标准气体校准或加标回收率作为验收和质控监督的基本方法。
通過對7種廢氣自動鑑測繫統的比較研究和現場測試,提齣瞭非分散紅外法、紫外差分法、紫外熒光法、化學髮光法等多種 SO2和 NO x 自動鑑測技術在低濃度範圍實現準確定量鑑測的性能評價方法,定義瞭 CEMS 的繫統檢齣限及其主要影響因素。建議採用繫統檢齣限、線性誤差等關鍵參數作為低濃度 CEMS 的性能評價方法,提齣將全繫統多點標準氣體校準或加標迴收率作為驗收和質控鑑督的基本方法。
통과대7충폐기자동감측계통적비교연구화현장측시,제출료비분산홍외법、자외차분법、자외형광법、화학발광법등다충 SO2화 NO x 자동감측기술재저농도범위실현준학정량감측적성능평개방법,정의료 CEMS 적계통검출한급기주요영향인소。건의채용계통검출한、선성오차등관건삼수작위저농도 CEMS 적성능평개방법,제출장전계통다점표준기체교준혹가표회수솔작위험수화질공감독적기본방법。
Based on the comparative studies and field testing on seven kinds of CEMS,the performance e-valuation methods of NDIR,UV-Difference,UV Fluorescence and Chemiluminescent were put forward for the ac-curate quantification of SO2 and NO x at low concentrations in flue gases form stationary sources.The system detec-tion limit of CEMS was defined and its main influencing factors were discussed.The system detection limit and linearity error were recommended to be key parameters of performance evaluation.Multi-point calibration or spiked recovery was suggested to be the base method of acceptance check and quality control.