CAJ | 학술논문

环糊精因其特殊的结构特点，尤其是经过交联剂改性的交联β-环糊精（MDI-β-CD），可以处理与其空腔尺寸匹配的苯酚污染物，具有更好的处理苯酚废水的能力。为进一步提高 MDI-β-CD 处理苯酚废水的效果，研究其在超声协同条件下的废水处理能力和适合工况。通过对MDI-β-CD用量、废水pH值、废水浓度、超声声强和频率的研究，找到处理苯酚废水的适合工艺条件：超声频率20 kHz，超声声强0.2 W/cm2，苯酚初始浓度100 mg/L，pH值6.0，溶液体积100 mL，反应温度40℃，吸附时间120 min，MDI-β-CD用量40 g/L；在此条件下， MDI-β-CD与超声协同处理苯酚废水吸附效率可以达到94.1%。
배호정인기특수적결구특점，우기시경과교련제개성적교련β-배호정（MDI-β-CD），가이처리여기공강척촌필배적분분오염물，구유경호적처리분분폐수적능력。위진일보제고 MDI-β-CD 처리분분폐수적효과，연구기재초성협동조건하적폐수처리능력화괄합공황。통과대MDI-β-CD용량、폐수pH치、폐수농도、초성성강화빈솔적연구，조도처리분분폐수적괄합공예조건：초성빈솔20 kHz，초성성강0.2 W/cm2，분분초시농도100 mg/L，pH치6.0，용액체적100 mL，반응온도40℃，흡부시간120 min，MDI-β-CD용량40 g/L；재차조건하， MDI-β-CD여초성협동처리분분폐수흡부효솔가이체도94.1%。
New functional materials crosslinkingβ-cyclodextrin(MDI-β-CD) can be used for better treatment of wastewater containing phenol because of the special structure. Modified crosslinkingβ-cyclodextrins has the ability to absorb phenol pollutants because of the porous structure. In order to improve treatment effects,the treatment abilities of MDI-β-CD and the suitable working conditions of the phenol wastewater were studied using ultrasonic. The dosage of MDI-β-CD , the pH and concentration of wastewater,ultra sound intensity and frequency were investigated. The suitable technological conditions of adsorption were determined as the following:pH 6.0,initial concentration 100 mg/L,wastewater volume 100 mL,new type crosslinking β-cyclodextrins 40 g/L,absorption temperature 40 ℃,absorption time 120 min. The ultrasound parameters were 0.2 W/cm2 of ultrasonic intensities and 20 kHz ultrasonic frequency. The absorption efficiency was up to 94.1%.