化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
3期
643-650
,共8页
王燕杰%应浩%孙云娟%江俊飞%余维金%许玉
王燕傑%應浩%孫雲娟%江俊飛%餘維金%許玉
왕연걸%응호%손운연%강준비%여유금%허옥
烘焙%稻壳%煤炭%共热解
烘焙%稻殼%煤炭%共熱解
홍배%도각%매탄%공열해
torrefaction%rice husk%coal%co-pyrolysis
稻壳在250℃/30 min条件下烘焙后,与无烟煤、烟煤和褐煤3种不同煤化程度煤进行不同比例的混合,混合物分别进行热重分析和高温共热解特性研究。结果表明:热重分析中,添加烘焙稻壳有利于提高无烟煤和烟煤的转化率,其提高率低于5%,但是不利于提高褐煤的转化率;高温共热解实验中,随着烘焙稻壳添加比例的提高,无烟煤和烟煤与烘焙稻壳共热解固体产物减少,气体产物增加,而褐煤与烘焙稻壳共热解固体产量增加,气体产量略有下降;烘焙稻壳的添加有利于共热解产气中H2组分的增加和CO2组分的减少,通过改变烘焙稻壳在混合物中的比例可以对共热解气体组分进行调节。
稻殼在250℃/30 min條件下烘焙後,與無煙煤、煙煤和褐煤3種不同煤化程度煤進行不同比例的混閤,混閤物分彆進行熱重分析和高溫共熱解特性研究。結果錶明:熱重分析中,添加烘焙稻殼有利于提高無煙煤和煙煤的轉化率,其提高率低于5%,但是不利于提高褐煤的轉化率;高溫共熱解實驗中,隨著烘焙稻殼添加比例的提高,無煙煤和煙煤與烘焙稻殼共熱解固體產物減少,氣體產物增加,而褐煤與烘焙稻殼共熱解固體產量增加,氣體產量略有下降;烘焙稻殼的添加有利于共熱解產氣中H2組分的增加和CO2組分的減少,通過改變烘焙稻殼在混閤物中的比例可以對共熱解氣體組分進行調節。
도각재250℃/30 min조건하홍배후,여무연매、연매화갈매3충불동매화정도매진행불동비례적혼합,혼합물분별진행열중분석화고온공열해특성연구。결과표명:열중분석중,첨가홍배도각유리우제고무연매화연매적전화솔,기제고솔저우5%,단시불리우제고갈매적전화솔;고온공열해실험중,수착홍배도각첨가비례적제고,무연매화연매여홍배도각공열해고체산물감소,기체산물증가,이갈매여홍배도각공열해고체산량증가,기체산량략유하강;홍배도각적첨가유리우공열해산기중H2조분적증가화CO2조분적감소,통과개변홍배도각재혼합물중적비례가이대공열해기체조분진행조절。
Rice husk was torrefied at the condition of 250 ℃/30 min,then blended it with anthracite, bituminous coal and lignite at different ratios,which had different coalification degrees. The mixtures were analyzed by Thermal Gravimetric Analyzer (TGA) and co-pyrolysis experiments. The results showed that torrefied rice husk had the advantage of raising conversion of the anthracite and bituminous coal by analyzing the TG curves,the increased rates were no more than 5%,but the torrefied rice husk had a negative effect on the conversion of lignite. In the experiments of co-pyrolysis,with the increase of torrefied rice husk in anthracite and bituminous coal,the solid products of the mixtures were lowered and the the gaseous products were increased,but the torrefied rice husk had an inhibitive effect on lignite. The addition of torrefied rice husk in the blends had the effect of accruing the content of H2 and reducing the content of CO2. So changing the percentage of torrefied rice husk in the mixtures had the effect of regulating the component of syngas.