功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2013年
21期
3183-3185,3189
,共4页
马保国%王景然%李相国%何超
馬保國%王景然%李相國%何超
마보국%왕경연%리상국%하초
固化%硝酸铅%pH 值%碳化%氯离子
固化%硝痠鉛%pH 值%碳化%氯離子
고화%초산연%pH 치%탄화%록리자
solidification%lead nitrate%pH value%carbonization%chloride ions
在不同pH 值、碳化、氯离子侵蚀条件下,利用磷酸镁水泥对不同掺量的硝酸铅进行固化。研究不同条件下重金属铅的浸出率规律,并对不同掺量的硝酸铅对磷酸镁水泥水化产物种类、水化产物形貌进行了探讨。研究表明,在 pH 值为2时,铅的浸出率最大,随着pH 值增加浸出率降低,但在 pH 值为12,浸出率又有所升高;在碳化条件下铅的浸出率随养护时间的延长先增加后趋于稳定;在氯离子侵蚀条件下,铅的浸出率随侵蚀时间的延长变化不明显。
在不同pH 值、碳化、氯離子侵蝕條件下,利用燐痠鎂水泥對不同摻量的硝痠鉛進行固化。研究不同條件下重金屬鉛的浸齣率規律,併對不同摻量的硝痠鉛對燐痠鎂水泥水化產物種類、水化產物形貌進行瞭探討。研究錶明,在 pH 值為2時,鉛的浸齣率最大,隨著pH 值增加浸齣率降低,但在 pH 值為12,浸齣率又有所升高;在碳化條件下鉛的浸齣率隨養護時間的延長先增加後趨于穩定;在氯離子侵蝕條件下,鉛的浸齣率隨侵蝕時間的延長變化不明顯。
재불동pH 치、탄화、록리자침식조건하,이용린산미수니대불동참량적초산연진행고화。연구불동조건하중금속연적침출솔규률,병대불동참량적초산연대린산미수니수화산물충류、수화산물형모진행료탐토。연구표명,재 pH 치위2시,연적침출솔최대,수착pH 치증가침출솔강저,단재 pH 치위12,침출솔우유소승고;재탄화조건하연적침출솔수양호시간적연장선증가후추우은정;재록리자침식조건하,연적침출솔수침식시간적연장변화불명현。
The solidification of magnesium phosphate cement with different content of nitric acid lead in different pH value,carbonization conditions and chloride ions.Heavy metal leaching rate law and the influence of differ-ent content of nitric acid lead on types and morphology of cement hydration products were studied.Research shows that:when the pH value was 2,lead leaching rate was largest,and as the pH value increased the leac-hing rate decreased.But the pH value was 12,leaching rate was slightly increased.The lead leaching rate would increase and then level-off in carbonization conditions.In chloride ions conditions,leaching rate of lead with the extension erosion time does not change significantly.