功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2013年
21期
3130-3134
,共5页
孙本哲%周思朗%王恒%祁阳
孫本哲%週思朗%王恆%祁暘
손본철%주사랑%왕항%기양
掺杂%非公度调制结构%超导临界转变开始温度%调制波矢%晶格失配
摻雜%非公度調製結構%超導臨界轉變開始溫度%調製波矢%晶格失配
참잡%비공도조제결구%초도림계전변개시온도%조제파시%정격실배
doping%incommensurate modulation structure%modulation wave vector%TC,onset%crystal misfit
采用溶胶-凝胶方法合成了名义组分为Bi2Sr2-xCaxCuO6+δ(x=0.1、0.3、0.5、0.7和0.9)的系列样品,运用 XRD、TEM和四引线法,研究了钙掺杂对Bi-2201相晶体结构、点阵参数、非公度调制结构和超导临界转变开始温度(T C,onset )的影响。研究发现,钙原子已进入到 Bi-2201单胞内部,在整个掺杂体系内,Bi-2201单胞都能够维持正交点阵;随着钙掺杂量增加,正交单胞的c 轴长度逐渐减小,而当x>0.3时,Bi-2201相调制波矢的b 轴分量逐渐减小,而c 轴分量有所上升;电阻随温度变化曲线表明,当x=0.3时,T C,onset 达到最高,之后有所下降,这与调制波矢在b 轴分量的变化相一致,这种变化能够用晶格失配模型很好地解释。
採用溶膠-凝膠方法閤成瞭名義組分為Bi2Sr2-xCaxCuO6+δ(x=0.1、0.3、0.5、0.7和0.9)的繫列樣品,運用 XRD、TEM和四引線法,研究瞭鈣摻雜對Bi-2201相晶體結構、點陣參數、非公度調製結構和超導臨界轉變開始溫度(T C,onset )的影響。研究髮現,鈣原子已進入到 Bi-2201單胞內部,在整箇摻雜體繫內,Bi-2201單胞都能夠維持正交點陣;隨著鈣摻雜量增加,正交單胞的c 軸長度逐漸減小,而噹x>0.3時,Bi-2201相調製波矢的b 軸分量逐漸減小,而c 軸分量有所上升;電阻隨溫度變化麯線錶明,噹x=0.3時,T C,onset 達到最高,之後有所下降,這與調製波矢在b 軸分量的變化相一緻,這種變化能夠用晶格失配模型很好地解釋。
채용용효-응효방법합성료명의조분위Bi2Sr2-xCaxCuO6+δ(x=0.1、0.3、0.5、0.7화0.9)적계렬양품,운용 XRD、TEM화사인선법,연구료개참잡대Bi-2201상정체결구、점진삼수、비공도조제결구화초도림계전변개시온도(T C,onset )적영향。연구발현,개원자이진입도 Bi-2201단포내부,재정개참잡체계내,Bi-2201단포도능구유지정교점진;수착개참잡량증가,정교단포적c 축장도축점감소,이당x>0.3시,Bi-2201상조제파시적b 축분량축점감소,이c 축분량유소상승;전조수온도변화곡선표명,당x=0.3시,T C,onset 체도최고,지후유소하강,저여조제파시재b 축분량적변화상일치,저충변화능구용정격실배모형흔호지해석。
A series of samples with the nominal composition of Bi2Sr2-xCaxCuO6+δ(x=0.1,0.3,0.5,0.7,0.9) were prepared by sol-gel method.By means of XRD,TEM and standard four-probe technique,it was investiga-ted that the effects of Ca doping on lattice types and parameters of Bi-2201 phase,the incommensurate modula-tion structure and the onset temperature of superconducting critical transition (TC,onset ).It was found that Bi-2201 phase with orthorhombic symmetry can be maintained with the introduction of Ca2+ in the whole doping range.With increasing x,lattice parameter c was decreasing gradually.When x>0.3,the b* component of the modulation wave vector was decreasing while the c* component was increasing with increasing x.Experi-mental R-T curves show that TC,onset was the highest when x=0.3,and then has a declining trend with increas-ing x,which was in agreement with the variation of the b* component of the modulation wave vector and can be interpreted by the crystal misfit model.