化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
7期
1856-1863
,共8页
廖圣良%商士斌%司红燕%饶小平%宋湛谦
廖聖良%商士斌%司紅燕%饒小平%宋湛謙
료골량%상사빈%사홍연%요소평%송담겸
松节油%蒎烯%加成反应%衍生物
鬆節油%蒎烯%加成反應%衍生物
송절유%파희%가성반응%연생물
turpentine%pinene%addition reaction%derivatives
松节油是世界上最主要的植物精油,具有很高的应用价值。α-蒎烯和β-蒎烯是松节油最主要的两个组成成分,以这两个化合物为原料,经过多种化学反应途径,可以合成众多具有高附加值的衍生化合物。然而,目前对上文提及的化学反应途径的系统介绍仍然比较缺乏。本文对α-蒎烯和β-蒎烯经过加成反应合成衍生物的研究进行了综述;介绍了α-蒎烯和β-蒎烯与氢气、水、氯化氢等8类化合物进行加成反应生成衍生物的合成方法的研究,并简述了这些衍生物的应用研究。展望了未来松节油衍生物合成研究的方向,指出合成具有特殊性能的衍生物具有重要意义。
鬆節油是世界上最主要的植物精油,具有很高的應用價值。α-蒎烯和β-蒎烯是鬆節油最主要的兩箇組成成分,以這兩箇化閤物為原料,經過多種化學反應途徑,可以閤成衆多具有高附加值的衍生化閤物。然而,目前對上文提及的化學反應途徑的繫統介紹仍然比較缺乏。本文對α-蒎烯和β-蒎烯經過加成反應閤成衍生物的研究進行瞭綜述;介紹瞭α-蒎烯和β-蒎烯與氫氣、水、氯化氫等8類化閤物進行加成反應生成衍生物的閤成方法的研究,併簡述瞭這些衍生物的應用研究。展望瞭未來鬆節油衍生物閤成研究的方嚮,指齣閤成具有特殊性能的衍生物具有重要意義。
송절유시세계상최주요적식물정유,구유흔고적응용개치。α-파희화β-파희시송절유최주요적량개조성성분,이저량개화합물위원료,경과다충화학반응도경,가이합성음다구유고부가치적연생화합물。연이,목전대상문제급적화학반응도경적계통개소잉연비교결핍。본문대α-파희화β-파희경과가성반응합성연생물적연구진행료종술;개소료α-파희화β-파희여경기、수、록화경등8류화합물진행가성반응생성연생물적합성방법적연구,병간술료저사연생물적응용연구。전망료미래송절유연생물합성연구적방향,지출합성구유특수성능적연생물구유중요의의。
Turpentine oil,the most important essential oil of the world,has a high application value.α-pinene andβ-pinene are two principle components of turpentine oil,using these two compounds, plenty of derivatives with high value-added can be synthesized through several reaction pathways. However some systematic introductions to those pathways mentioned above are still deficient. This paper reviewed the research progress on synthesis of derivatives from addition reactions ofα-pinene orβ-pinene. Methods applied in that α-pinene or β-pinene reacted with eight kind of compounds (including H2,H2O,HCl,etc.) were introduced intensively;applications of the derivatives from these reactions were mentioned as well. Finally,a prospect was given to the future research on synthesis of turpentine oil derivatives;it was believed that synthesis of derivatives with specific properties might be of great importance.