新型炭材料
新型炭材料
신형탄재료
NEW CARBON MATERIALS
2014年
2期
96-101
,共6页
高峰%王媛%李存梅%徐志雄%张长明%王建龙%李开喜
高峰%王媛%李存梅%徐誌雄%張長明%王建龍%李開喜
고봉%왕원%리존매%서지웅%장장명%왕건룡%리개희
活性炭%吸附%CO2%改性
活性炭%吸附%CO2%改性
활성탄%흡부%CO2%개성
Activated carbon%Adsorption%CO2%Modification
采用硝化-还原法对高比表面积活性炭进行改性以提高其对CO2的吸附性能。利用氮吸附、FT-IR、元素分析、XPS等方法对改性前后的样品进行表征,并通过高压吸附装置测试CO2吸附性能。结果表明,改性样品对CO2的吸附量在室温下和319.15 K下分别为17.72 mmol/g和14.01 mmol/g,比原样分别提高了49%和70%(单位比表面积吸附量的增加幅度),这可能与改性样品的表面连接了碱性较强的伯氨基等含氮官能团有关。改性样品经4轮缓和条件下的吸附-脱附循环后,吸附量未明显下降,表明改性样品仍以物理吸附为主。
採用硝化-還原法對高比錶麵積活性炭進行改性以提高其對CO2的吸附性能。利用氮吸附、FT-IR、元素分析、XPS等方法對改性前後的樣品進行錶徵,併通過高壓吸附裝置測試CO2吸附性能。結果錶明,改性樣品對CO2的吸附量在室溫下和319.15 K下分彆為17.72 mmol/g和14.01 mmol/g,比原樣分彆提高瞭49%和70%(單位比錶麵積吸附量的增加幅度),這可能與改性樣品的錶麵連接瞭堿性較彊的伯氨基等含氮官能糰有關。改性樣品經4輪緩和條件下的吸附-脫附循環後,吸附量未明顯下降,錶明改性樣品仍以物理吸附為主。
채용초화-환원법대고비표면적활성탄진행개성이제고기대CO2적흡부성능。이용담흡부、FT-IR、원소분석、XPS등방법대개성전후적양품진행표정,병통과고압흡부장치측시CO2흡부성능。결과표명,개성양품대CO2적흡부량재실온하화319.15 K하분별위17.72 mmol/g화14.01 mmol/g,비원양분별제고료49%화70%(단위비표면적흡부량적증가폭도),저가능여개성양품적표면련접료감성교강적백안기등함담관능단유관。개성양품경4륜완화조건하적흡부-탈부순배후,흡부량미명현하강,표명개성양품잉이물리흡부위주。
Activated carbon was oxidized by an acid mixture of concentrated HNO3 and H2 SO4 with a volume ratio of 1:1 diluted with the same volume of de-ionized water, followed by reduction with iron dust to modify its surface chemical properties for CO2 ad-sorption. The samples before and after the modification were characterized by N2 adsorption, elemental analysis, FT-IR and XPS. CO2 adsorption properties of the samples were investigated by high pressure adsorption. It was found that the adsorption capacities of the modified sample were 17. 72 and 14. 01 mmol/g at room temperature and 319. 15 K respectively, showing an increase of 49 and 70% respectively, based on the surface area of the samples. The modified activated carbon can be recycled 4 times at ambient condi-tions without a significant decrease in CO2 adsorption capacity. Surface basic nitrogen-containing functional groups on the modified sample, such as primary amino groups, are responsible for the increased adsorption.