动力工程学报
動力工程學報
동력공정학보
JOURNAL OF POWER ENGINEERING
2012年
11期
878-884,897
,共8页
热重分析%城市污泥%混烧%燃烧特性%动力学参数
熱重分析%城市汙泥%混燒%燃燒特性%動力學參數
열중분석%성시오니%혼소%연소특성%동역학삼수
thermogravimetric analysis~ municipal sewage sludge%co-firing%combustion characteristickinetic parameter
采用热重分析法对1种煤样(C)和2种城市污水污泥(S1和S2)及其混合试样进行了燃烧特性试验研究.结果表明:污泥的失重主要为挥发分的析出与燃烧,升温速率提高有助于污泥的快速处理及热能的利用,但总失重率较小,减量化较差;污泥与煤样的混烧特性从总体上表现为污泥和煤样共同作用的结果,随着污泥所占比例的增加,试样的着火温度逐渐降低;当污泥的掺烧比为25%左右时,综合燃烧性能最好.采用Freeman-Carroll微分法确定污泥与煤混烧过程中化学动力学参数,结果显示污泥在温度较低时更易于反应,而煤则表现出相反的性质.根据对不同掺烧比下污泥燃烧性能参数及化学动力学等方面的分析,得出污泥S2更适合燃烧处理.
採用熱重分析法對1種煤樣(C)和2種城市汙水汙泥(S1和S2)及其混閤試樣進行瞭燃燒特性試驗研究.結果錶明:汙泥的失重主要為揮髮分的析齣與燃燒,升溫速率提高有助于汙泥的快速處理及熱能的利用,但總失重率較小,減量化較差;汙泥與煤樣的混燒特性從總體上錶現為汙泥和煤樣共同作用的結果,隨著汙泥所佔比例的增加,試樣的著火溫度逐漸降低;噹汙泥的摻燒比為25%左右時,綜閤燃燒性能最好.採用Freeman-Carroll微分法確定汙泥與煤混燒過程中化學動力學參數,結果顯示汙泥在溫度較低時更易于反應,而煤則錶現齣相反的性質.根據對不同摻燒比下汙泥燃燒性能參數及化學動力學等方麵的分析,得齣汙泥S2更適閤燃燒處理.
채용열중분석법대1충매양(C)화2충성시오수오니(S1화S2)급기혼합시양진행료연소특성시험연구.결과표명:오니적실중주요위휘발분적석출여연소,승온속솔제고유조우오니적쾌속처리급열능적이용,단총실중솔교소,감양화교차;오니여매양적혼소특성종총체상표현위오니화매양공동작용적결과,수착오니소점비례적증가,시양적착화온도축점강저;당오니적참소비위25%좌우시,종합연소성능최호.채용Freeman-Carroll미분법학정오니여매혼소과정중화학동역학삼수,결과현시오니재온도교저시경역우반응,이매칙표현출상반적성질.근거대불동참소비하오니연소성능삼수급화학동역학등방면적분석,득출오니S2경괄합연소처리.
Combustion characteristic experiments were respectively performed for one coal sample(C), two municipal sewage sludge samples ($1, $2) and their mixtures using thermogravimetric analysis. Results show that the sludge weight loss mainly results from the separation and combustion of volatile compo- nents. Raising the heating rate may help to speed up the sludge disposal, but may decrease both the total weight loss rate and the quantity reduction effect. The co-firing performance of sludge with coal generally expresses the joint action of both the fuels; with the increase of sludge ratio, ignition temperature of the mixture reduces gradually; the comprehensive combustion performance index reaches the maximum at a sludge ratio of 25%. Besides, the kinetic parameters obtained by using the Freeman-Carroll differentiation prove the sludge to be more active at low temperatures, while the coal behaves in an opposite way, Based on analysis of combustion characteristics and chemical kinetics of sludge at different blending ratios, the combustion treatment is believed to be more suitable for sludge $2.