山西化工
山西化工
산서화공
SHANXI CHEMICAL INDUSTRY
2012年
4期
5-6
,共2页
刘海龙%陈昊然%王会娟%焦红权%徐亚琳%李海涛
劉海龍%陳昊然%王會娟%焦紅權%徐亞琳%李海濤
류해룡%진호연%왕회연%초홍권%서아림%리해도
炭包覆改性氧化铝%水热稳定性%焙烧温度
炭包覆改性氧化鋁%水熱穩定性%焙燒溫度
탄포복개성양화려%수열은정성%배소온도
carbon covered y-Al2O3%hydrothermal stability%calcination temperature
通过不同温度焙烧蔗糖/氧化铝前驱体的方法制备了炭包覆改性氧化铝(CCA),对该材料进行水热处理,并采用XRD、TG-DSC对水热处理前、后的样品进行表征。结果表明,焙烧温度在300℃时,产生软焦质炭物种,显著地抑制了Al2O3水合反应;提高焙烧温度可以获得稳定存在的聚合或浓缩的炭物种,但对Al2O3水合的抑制程度降低。
通過不同溫度焙燒蔗糖/氧化鋁前驅體的方法製備瞭炭包覆改性氧化鋁(CCA),對該材料進行水熱處理,併採用XRD、TG-DSC對水熱處理前、後的樣品進行錶徵。結果錶明,焙燒溫度在300℃時,產生軟焦質炭物種,顯著地抑製瞭Al2O3水閤反應;提高焙燒溫度可以穫得穩定存在的聚閤或濃縮的炭物種,但對Al2O3水閤的抑製程度降低。
통과불동온도배소자당/양화려전구체적방법제비료탄포복개성양화려(CCA),대해재료진행수열처리,병채용XRD、TG-DSC대수열처리전、후적양품진행표정。결과표명,배소온도재300℃시,산생연초질탄물충,현저지억제료Al2O3수합반응;제고배소온도가이획득은정존재적취합혹농축적탄물충,단대Al2O3수합적억제정도강저。
Carbon covered y-Al2O3 (CCA) was prepared by calcination of suerose/Al2O3 at different temperatures. The samples before and after hydrothermal treatment were characterized by XRD and TG-DSC. The results indicated that the soft carbon species emerged at the calcination temperature of 300 ℃, and inhabited the hydration of support y-Al2O3. While the stable concentrated carbon species were obtained by improving the calcination temperature, the inhabition of hydration of support y-Al2 O3 decreased.