现代涂料与涂装
現代塗料與塗裝
현대도료여도장
MODERN PAINT & FINISHING
2012年
9期
1-2,30
,共3页
魏铭%黄雪%刘铭%刘晓芳%姚娃铭%董月林
魏銘%黃雪%劉銘%劉曉芳%姚娃銘%董月林
위명%황설%류명%류효방%요왜명%동월림
无溶剂%水性聚氨酯%乳液
無溶劑%水性聚氨酯%乳液
무용제%수성취안지%유액
solvent-free,waterborne polyurethane%emulsion
采用预聚体法合成无溶剂水性聚氨酯。探讨了扩链剂的添加顺序,nNCO/nOH比例、二羟甲基丙酸(DMP))含量等因素对水性聚氨酯乳液性能的影响。结果表明:当nNCO/nOH比例为1.3左右,DMPA用量为6%,先添加亲水性扩链剂DMPA时,乳液的综合性能最佳。
採用預聚體法閤成無溶劑水性聚氨酯。探討瞭擴鏈劑的添加順序,nNCO/nOH比例、二羥甲基丙痠(DMP))含量等因素對水性聚氨酯乳液性能的影響。結果錶明:噹nNCO/nOH比例為1.3左右,DMPA用量為6%,先添加親水性擴鏈劑DMPA時,乳液的綜閤性能最佳。
채용예취체법합성무용제수성취안지。탐토료확련제적첨가순서,nNCO/nOH비례、이간갑기병산(DMP))함량등인소대수성취안지유액성능적영향。결과표명:당nNCO/nOH비례위1.3좌우,DMPA용량위6%,선첨가친수성확련제DMPA시,유액적종합성능최가。
Solvent-free waterborne polyurethane was synthesized by adopting prepolymer method. The influence on the properties of an aqueous polyurethane emulsion effect such as the adding order of the chain extender, nNCO/nOH proportion and the content of dimethylol propionic acid (DMPA) were studied. The results show that the emulsion has the optimum comprehensive properties when the nNCO/nOH was around 1.3, the dosage of DMPA is 6%, and firstly add the hydrophilic chain extender DMPA.