CAJ | 학술논문

主要研究钯电极型离子聚合物-金属复合材料(Pd-ionic polymer-metal composite,Pd-IPMC)的制备工艺.以增加 Pd-IPMC 的电致动位移为优化目标,采用正交优化方法,针对浸泡还原镀和化学镀两个核心步骤进行了参数优化,探索了主要工艺参数对材料电致位移的影响规律.实验结果给出了工艺参数的优化值,以及这些参数对材料性能的影响水平和效应曲线.由优化后工艺参数制备的 Pd-IPMC 性能较优化前有显著提高,且优于 ERI 公司商业化的 IPMC.研究结果充分验证了 Pd 作为 IPMC 电极的可行性,解决了现有 Pd-IPMC 材料致动性能不理想的难题,对于制备低成本、大变形的 IPMC 材料,并促进其工程应用具有重要意义.
주요연구파전겁형리자취합물-금속복합재료(Pd-ionic polymer-metal composite,Pd-IPMC)적제비공예.이증가 Pd-IPMC 적전치동위이위우화목표,채용정교우화방법,침대침포환원도화화학도량개핵심보취진행료삼수우화,탐색료주요공예삼수대재료전치위이적영향규률.실험결과급출료공예삼수적우화치,이급저사삼수대재료성능적영향수평화효응곡선.유우화후공예삼수제비적 Pd-IPMC 성능교우화전유현저제고,차우우 ERI 공사상업화적 IPMC.연구결과충분험증료 Pd 작위 IPMC 전겁적가행성,해결료현유 Pd-IPMC 재료치동성능불이상적난제,대우제비저성본、대변형적 IPMC 재료,병촉진기공정응용구유중요의의.
This paper mainly focused on the manufacturing process for Pd-IPMC.In order to improve the electro-active displacement of Pd-IPMC,the main parameters in the two core steps,the impregnation-reduction plating (IRP)and the autocatalytic plating (ACP),were optimized with an orthogonal array method.Furthermore,the influences of these parameters on the final displacement were analyzed and the optimized value,effect ranges and effect curve for the manufacturing parameters were presented.In addition,Pd-IPMC manufactured with the optimized parameters showed significant improvement in the displacement and exhibits better performance than the Pt-IPMC and Pd-IPMC purchased from ERI.This research verified the feasibility of using Pd as electrode for IPMC and greatly improved the unsatisfied performance of current Pd-IPMC;therefore,it will be of great significance for guiding the manufacture of low-cost,large-displacement IPMC materials and will promote their industrial application.