信阳师范学院学报(自然科学版)
信暘師範學院學報(自然科學版)
신양사범학원학보(자연과학판)
JOURNAL OF XINYANG NORMAL UNIVERSITY(NATURAL SCIENCE EDITION)
2013年
4期
573-576
,共4页
韩金土%楚明超%张继宗
韓金土%楚明超%張繼宗
한금토%초명초%장계종
钴铁纳米复合材料%β-环糊精%对苯二酚%电化学传感器
鈷鐵納米複閤材料%β-環糊精%對苯二酚%電化學傳感器
고철납미복합재료%β-배호정%대분이분%전화학전감기
cobalt ferrite nanocomposite%β-cyclodextrin%hydroquinone%electrochemical sensor
基于β-环糊精钴铁氧化物纳米复合材料研制了一种新型灵敏的电化学传感器,并用于测定对苯二酚.由于在电极上对苯二酚具有高的负载容量和钴铁氧化物直立的导电性,制作的传感器的电化学响应大大提高.结果表明:该方法的线性范围为1~200μmol/L,检出限为0.12μmol/L (RSN =3).所研制的电化学传感器具有良好的选择性和重现性,对对苯二酚合成水样进行了测定,回收率在96.0%~103.5%之间.
基于β-環糊精鈷鐵氧化物納米複閤材料研製瞭一種新型靈敏的電化學傳感器,併用于測定對苯二酚.由于在電極上對苯二酚具有高的負載容量和鈷鐵氧化物直立的導電性,製作的傳感器的電化學響應大大提高.結果錶明:該方法的線性範圍為1~200μmol/L,檢齣限為0.12μmol/L (RSN =3).所研製的電化學傳感器具有良好的選擇性和重現性,對對苯二酚閤成水樣進行瞭測定,迴收率在96.0%~103.5%之間.
기우β-배호정고철양화물납미복합재료연제료일충신형령민적전화학전감기,병용우측정대분이분.유우재전겁상대분이분구유고적부재용량화고철양화물직립적도전성,제작적전감기적전화학향응대대제고.결과표명:해방법적선성범위위1~200μmol/L,검출한위0.12μmol/L (RSN =3).소연제적전화학전감기구유량호적선택성화중현성,대대분이분합성수양진행료측정,회수솔재96.0%~103.5%지간.
An electrochemical sensor based on β-cyclodextrin-cobalt ferrite nanocomposite was developed for the sensitive detection of hydroquinone ( HQ) .Due to the high hydroquinone-loading capacity on the electrode surface and the upstanding electric conductivity of cobalt ferrite nanocomposite , the electrochemical response of the fabricated sen-sor was greatly enhanced .The results showed that the electrochemical response of the fabricated sensor displayed excell-lent analytical performance for hydroquinone detection from 1 to 200μmol/L with a low detection limit of 0.12 μmol/L (RSN =3).Moreover, the developed electrochemical sensor exhibited good selectivity and acceptable reproduc -ibility and could be used for the detection of hydroquinone in water samples with the recovery of 96.0%~103.5%.