西华师范大学学报:自然科学版
西華師範大學學報:自然科學版
서화사범대학학보:자연과학판
Journal of China West Normal University:Natural Science Edition
2012年
1期
96-101
,共6页
郑时国%辜天彬%詹豪强%刘向凯%张亚丽%夏世威
鄭時國%辜天彬%詹豪彊%劉嚮凱%張亞麗%夏世威
정시국%고천빈%첨호강%류향개%장아려%하세위
聚苯胺%水溶性聚合物%聚合%共轭
聚苯胺%水溶性聚閤物%聚閤%共軛
취분알%수용성취합물%취합%공액
polyaniline%water-soluble polymer%polymerization%conjugation
报道了一种新型水溶性聚苯胺衍生物的化学合成,并通过红外光谱、紫外-可见光谱、循环伏安法、X-射线衍射和溶解率测定对其结构与性能进行了研究.研究结果表明:这种聚苯胺衍生物共轭性差,不具有电活性,可能是不导电的;呈现出非晶态结构;在水、乙醇、氯仿、N,N-二甲基甲酰胺等普通溶剂中具有较好的溶解性.
報道瞭一種新型水溶性聚苯胺衍生物的化學閤成,併通過紅外光譜、紫外-可見光譜、循環伏安法、X-射線衍射和溶解率測定對其結構與性能進行瞭研究.研究結果錶明:這種聚苯胺衍生物共軛性差,不具有電活性,可能是不導電的;呈現齣非晶態結構;在水、乙醇、氯倣、N,N-二甲基甲酰胺等普通溶劑中具有較好的溶解性.
보도료일충신형수용성취분알연생물적화학합성,병통과홍외광보、자외-가견광보、순배복안법、X-사선연사화용해솔측정대기결구여성능진행료연구.연구결과표명:저충취분알연생물공액성차,불구유전활성,가능시불도전적;정현출비정태결구;재수、을순、록방、N,N-이갑기갑선알등보통용제중구유교호적용해성.
In this paper,the chemical synthesis of a novel water-soluble polyaniline derivative was reported and its structure and properties were studied by FTIR,UV-Vis,XRD,cyclic voltammetry and determination of solubility.The results indicated that this polyaniline derivative was poorly conjugated,had no electroactivity,exhibited an amorphous structure,and had preferable solublity in some common solvents like water,ethanol,chloroform and N,N-dimethyl formamide,etc.