CAJ | 학술논문

根据β-环糊精（β-CD）分子形态和空腔的结构特性，分析和探讨了β-CD与6种不同纤维的反应历程，分别为：通过以环氧基为交联桥，制备β-CD接枝纤维素纤维；采用β-CD和1，2，3，4-丁烷四羧酸对羊毛织物进行接枝研究；利用含磺酸基的β-CD对聚酰胺纤维进行改性，将β-CD接枝到聚酰胺纤维上；选用乙二醛或戊二醛为交联剂改性壳聚糖生成交联结构并接枝到壳聚糖纤维上；以邻碘酰基苯甲酸为氧化剂合成环糊精单醛，在弱酸性的条件下通过还原氨化反应接枝到蚕丝纤维上；利用β-CD与多元羧酸反应所得的共聚物接枝聚酯纤维。
근거β-배호정（β-CD）분자형태화공강적결구특성，분석화탐토료β-CD여6충불동섬유적반응역정，분별위：통과이배양기위교련교，제비β-CD접지섬유소섬유；채용β-CD화1，2，3，4-정완사최산대양모직물진행접지연구；이용함광산기적β-CD대취선알섬유진행개성，장β-CD접지도취선알섬유상；선용을이철혹무이철위교련제개성각취당생성교련결구병접지도각취당섬유상；이린전선기분갑산위양화제합성배호정단철，재약산성적조건하통과환원안화반응접지도잠사섬유상；이용β-CD여다원최산반응소득적공취물접지취지섬유。
According to the structural characterization of β-CD,the reaction processes and mechanism of the grafting reaction of β-CD onto six different fibers is put forward.β-CD grafted cellulose fiber is pre pared with epoxy group as cross-linking bridge;wool fibers is grafted with β-CD and BTCA. The polyamide fibers is modified with β-CD sulfonic acid for grafting β-CD; chitosan fiber is modified by glyoxal or glutaraldehyde as cross-linking agent,and then β-CD is grafted on the Chitosan fibers. Silk fiber grafted with β-CD is prepared in an acidic medium by coupling β-CD monoaldehyde to silk fiber in the presence of sodium cyanoborohydride. β-CD is grafted into polyester fiber by copolymer from the reaction β-CD and PCA.