陕西师范大学学报:自然科学版
陝西師範大學學報:自然科學版
협서사범대학학보:자연과학판
Journal of Shaanxi Normal University: Nat Sci Ed
2012年
2期
29-34
,共6页
宋武辉%杨敬娜%刘倩%赵小刚%程琳%梁海荣%闫妍%刘鹏
宋武輝%楊敬娜%劉倩%趙小剛%程琳%樑海榮%閆妍%劉鵬
송무휘%양경나%류천%조소강%정림%량해영%염연%류붕
弛豫性%铁电性能%电致应变
弛豫性%鐵電性能%電緻應變
이예성%철전성능%전치응변
relaxation behavior%ferroelectric property%electric field-induced strain
采用固相反应法,制备了(1-x)BNKT2-xBCT无铅压电陶瓷.研究了BCT加入对其相结构、介电、铁电、电致应变性能的影响.实验结果表明:在设定条件下,所有样品都形成了纯的钙钛矿结构,且在x=0.04~0.08之间处于四方相和伪立方相的过渡区域.材料去极化温度趋向于室温附近.弛豫性增强(γ=1.94),强烈削弱了材料的铁电性,使得剩余极化强度和压电系数减小很多.在x=0.04组分附近应变量达到最大值(0.122%),d33*达到230pm/V.
採用固相反應法,製備瞭(1-x)BNKT2-xBCT無鉛壓電陶瓷.研究瞭BCT加入對其相結構、介電、鐵電、電緻應變性能的影響.實驗結果錶明:在設定條件下,所有樣品都形成瞭純的鈣鈦礦結構,且在x=0.04~0.08之間處于四方相和偽立方相的過渡區域.材料去極化溫度趨嚮于室溫附近.弛豫性增彊(γ=1.94),彊烈削弱瞭材料的鐵電性,使得剩餘極化彊度和壓電繫數減小很多.在x=0.04組分附近應變量達到最大值(0.122%),d33*達到230pm/V.
채용고상반응법,제비료(1-x)BNKT2-xBCT무연압전도자.연구료BCT가입대기상결구、개전、철전、전치응변성능적영향.실험결과표명:재설정조건하,소유양품도형성료순적개태광결구,차재x=0.04~0.08지간처우사방상화위립방상적과도구역.재료거겁화온도추향우실온부근.이예성증강(γ=1.94),강렬삭약료재료적철전성,사득잉여겁화강도화압전계수감소흔다.재x=0.04조분부근응변량체도최대치(0.122%),d33*체도230pm/V.
The(1-x)BNKT2-xBCT lead free ceramics are prepared by the conventional solid-state sintering process.The phase components,dielectric,ferroelectric properties and electric field-induced strain with BCT are investigated.It is indicated that under the demanded condition all samples are pure perovskite structure,tetragonal and pseudo-cubic phase transition region exists in the range of x=0.04 to 0.08.The depolarization temperature of the material tend to room temperature and relaxation enhancements to γ=1.94.The ferroelectric of the material is weakened strongly,making the remanent polarization and piezoelectric coefficient appears significant reduction.Near the x=0.04 strain reached maximun 0.122%,d33* reached 230 pm/V.