中国涂料
中國塗料
중국도료
CHINA PAINT
2012年
2期
49-52
,共4页
张安杰%罗志河%张先宏%陈丽丽%雍涛%张海银
張安傑%囉誌河%張先宏%陳麗麗%雍濤%張海銀
장안걸%라지하%장선굉%진려려%옹도%장해은
光催化%自清洁:亲水性%抗沾污%涂料
光催化%自清潔:親水性%抗霑汙%塗料
광최화%자청길:친수성%항첨오%도료
photocatalytic%self-cleaning%hydrophilicity%contamination resistance%coatings
以钛酸丁酯、正硅酸乙酯为前躯体,采用溶胶-凝胶法低温制备具有光催化活性的纳米TiO2/SiO2复合薄膜,并且考察了试验温度、pH值、涂覆层数、搅拌速度等因素对涂层亲水性能的影响。结果表明:试验温度为5℃、pH值=2.5、TiO2质量分数为50%、涂覆层数为3层、转速为1500r/min时所制得的TiO2/SiO2复合薄膜的接触角最小为6.8°。通过光催化和户外试验,表明自制的自清洁涂料具有良好的光催化效果与抗沾污性能。
以鈦痠丁酯、正硅痠乙酯為前軀體,採用溶膠-凝膠法低溫製備具有光催化活性的納米TiO2/SiO2複閤薄膜,併且攷察瞭試驗溫度、pH值、塗覆層數、攪拌速度等因素對塗層親水性能的影響。結果錶明:試驗溫度為5℃、pH值=2.5、TiO2質量分數為50%、塗覆層數為3層、轉速為1500r/min時所製得的TiO2/SiO2複閤薄膜的接觸角最小為6.8°。通過光催化和戶外試驗,錶明自製的自清潔塗料具有良好的光催化效果與抗霑汙性能。
이태산정지、정규산을지위전구체,채용용효-응효법저온제비구유광최화활성적납미TiO2/SiO2복합박막,병차고찰료시험온도、pH치、도복층수、교반속도등인소대도층친수성능적영향。결과표명:시험온도위5℃、pH치=2.5、TiO2질량분수위50%、도복층수위3층、전속위1500r/min시소제득적TiO2/SiO2복합박막적접촉각최소위6.8°。통과광최화화호외시험,표명자제적자청길도료구유량호적광최화효과여항첨오성능。
This paper introduces the method of sol-gel to prepare nano TiO2/SiO2 composite coating with photocatalytic activity at low temperature with tetra-n-butyl titanate and ethyl silicate as former body; analyzes the influence of temperature, PH value, layer number and stirring speed on the hydrophilicity of the coating. Result turns out to be that, under the condition of 5 ℃, pH=2.5, TiO, content of 50%, 3 layers, rotational speed of 1500 r/min, the contact angle of TiO:/SiO: composite film can reach a minimum of 6.8°. Outdoor experiment and photocatalysis indicates that our self-cleansing coatings are of excellent contamination resistance and photocatalysis effect.