广州化学
廣州化學
엄주화학
GUANGZHOU CHEMISTRY
2012年
1期
27-31
,共5页
韩静磊%贺德春%王志良%贺蕴普%许振成
韓靜磊%賀德春%王誌良%賀蘊普%許振成
한정뢰%하덕춘%왕지량%하온보%허진성
养殖废水%高效液相色谱%抗生素%残留特征
養殖廢水%高效液相色譜%抗生素%殘留特徵
양식폐수%고효액상색보%항생소%잔류특정
swine wastewater%high performance liquid chromatography%antibiotic%residual characteristic
2010年调查了海南省6家规模化养猪场抗生素使用品种及来源,并采集养殖废水样品,用高效液相色谱紫外检测器检测了样品中4种四环素(四环素、土霉素、金霉素和强力霉素)和8种磺胺类药物(磺胺嘧啶、磺胺甲噻唑、磺胺噻唑、磺胺二甲基嘧啶、磺胺氯哒嗪、磺胺邻二甲氧嘧啶、磺胺间二甲氧嘧啶和磺胺喹恶啉)的残留浓度水平。结果显示,6家养殖场废水中土霉素、四环素和磺胺嘧啶的检出率及检出浓度较高,其中土霉素检出率为100%,最高浓度为71.75μg/L;四环素检出率为63%,最高检出浓度为24.83μg/L;磺胺嘧啶检出率为83%,最高检出浓度为17.69μg/L。4种四环素类检出总量变化范围为18.25~99.64μg/L,8种磺胺类检出总量变化范围为3.45~24.49μg/L;从养殖规模上看,小规模养殖场抗生素类检出品种较多,检出浓度也较高。
2010年調查瞭海南省6傢規模化養豬場抗生素使用品種及來源,併採集養殖廢水樣品,用高效液相色譜紫外檢測器檢測瞭樣品中4種四環素(四環素、土黴素、金黴素和彊力黴素)和8種磺胺類藥物(磺胺嘧啶、磺胺甲噻唑、磺胺噻唑、磺胺二甲基嘧啶、磺胺氯噠嗪、磺胺鄰二甲氧嘧啶、磺胺間二甲氧嘧啶和磺胺喹噁啉)的殘留濃度水平。結果顯示,6傢養殖場廢水中土黴素、四環素和磺胺嘧啶的檢齣率及檢齣濃度較高,其中土黴素檢齣率為100%,最高濃度為71.75μg/L;四環素檢齣率為63%,最高檢齣濃度為24.83μg/L;磺胺嘧啶檢齣率為83%,最高檢齣濃度為17.69μg/L。4種四環素類檢齣總量變化範圍為18.25~99.64μg/L,8種磺胺類檢齣總量變化範圍為3.45~24.49μg/L;從養殖規模上看,小規模養殖場抗生素類檢齣品種較多,檢齣濃度也較高。
2010년조사료해남성6가규모화양저장항생소사용품충급래원,병채집양식폐수양품,용고효액상색보자외검측기검측료양품중4충사배소(사배소、토매소、금매소화강력매소)화8충광알류약물(광알밀정、광알갑새서、광알새서、광알이갑기밀정、광알록달진、광알린이갑양밀정、광알간이갑양밀정화광알규악람)적잔류농도수평。결과현시,6가양식장폐수중토매소、사배소화광알밀정적검출솔급검출농도교고,기중토매소검출솔위100%,최고농도위71.75μg/L;사배소검출솔위63%,최고검출농도위24.83μg/L;광알밀정검출솔위83%,최고검출농도위17.69μg/L。4충사배소류검출총량변화범위위18.25~99.64μg/L,8충광알류검출총량변화범위위3.45~24.49μg/L;종양식규모상간,소규모양식장항생소류검출품충교다,검출농도야교고。
Antibiotics types and sources of wastewater from 6 large-scale piggery farms in Hainan Province were investigated in 2010.Residual concentrations of 4 types of tetracycline(tetracycline,oxytetracycline,chlortetracycline and doxycycline) and 8 types of sulfonamide(sulfadiazine,sulfamethylthiazole,sulfathiazole,sulfamethazine,nefrosulrenalsulfa,fanasil,sulfadlmethdme and sulfaquinoxaline) were determined by high performance liquid chromatography-UV detector.Results revealed that the incidence of detection was 100%,63% and 83%,the highest concentration was 71.75,24.83 μg/L and 17.69 μg/L for oxytetracycline,sulfadiazine and sulfadiazine respectively,were higher than other antibiotics.The amount of tetracyclines and sulfonamides were 18.25~99.64 μg/L and 3.45~24.49 μg/L,respectively.More types of antibiotic and higher concentration were detected at relatively small farms.