三峡环境与生态
三峽環境與生態
삼협배경여생태
CHONGQING ENVIRONMENTAL SCIENCE
2012年
3期
12-15,59
,共5页
金冰冰%蒋孝佳%华攀%高寒%潘理黎
金冰冰%蔣孝佳%華攀%高寒%潘理黎
금빙빙%장효가%화반%고한%반리려
实验室化学废液%废液无害化%铁炭微电解%Fenton法
實驗室化學廢液%廢液無害化%鐵炭微電解%Fenton法
실험실화학폐액%폐액무해화%철탄미전해%Fenton법
laboratory chemical waste%waste minimization%ferric carbon micro electrolysis%Fenton method
针对我国高校实验室高浓度化学废液污染的难题,设计了铁炭微电解一超声波-Fenton法-絮凝沉淀组合处理技术。铁炭微电解的优化工艺条件为:pH=4,V(Fe):V(c)-2:1,固液比为1:4,反应时间60min,循环反应2次;Fenton氧化工艺条件为:pH=4,投加Fenton试剂,反应时间60min;絮凝沉淀反应条件为:pH值为7,投加PAM5mg/L,PAC300mg/L。试验结果表明,废液COD。,总去除率达90%,且生化性明显提高,为高校实验室高浓度化学废液无害化处理探索可行的途径。
針對我國高校實驗室高濃度化學廢液汙染的難題,設計瞭鐵炭微電解一超聲波-Fenton法-絮凝沉澱組閤處理技術。鐵炭微電解的優化工藝條件為:pH=4,V(Fe):V(c)-2:1,固液比為1:4,反應時間60min,循環反應2次;Fenton氧化工藝條件為:pH=4,投加Fenton試劑,反應時間60min;絮凝沉澱反應條件為:pH值為7,投加PAM5mg/L,PAC300mg/L。試驗結果錶明,廢液COD。,總去除率達90%,且生化性明顯提高,為高校實驗室高濃度化學廢液無害化處理探索可行的途徑。
침대아국고교실험실고농도화학폐액오염적난제,설계료철탄미전해일초성파-Fenton법-서응침정조합처리기술。철탄미전해적우화공예조건위:pH=4,V(Fe):V(c)-2:1,고액비위1:4,반응시간60min,순배반응2차;Fenton양화공예조건위:pH=4,투가Fenton시제,반응시간60min;서응침정반응조건위:pH치위7,투가PAM5mg/L,PAC300mg/L。시험결과표명,폐액COD。,총거제솔체90%,차생화성명현제고,위고교실험실고농도화학폐액무해화처리탐색가행적도경。
In order to properly deal with chemical waste from university laboratory, experiments are designed using combined iron carbon micro electrolysis-uhrasound-Fenton-flocculation precipitation technology , to explore the suit- able condition for chemical waste removal. Results suggest optimized condition for iron carbon micro electrolysis process regester: pH=4,V( Fe ): V( C ) = 2:1, solid-liquid ratio is 1:4, reaction time regesters 60 min, cycled the reaction twice; the condition for fenton oxidation process is: pH=4, Fenton reagent addiction, 60min for reac- tion time; while conditions for the coagulation sedimentation reaction appear to be : pH=7, the dosage of PAM is 5 mg/L and PAC is 300 mg/L . Experimental results suggest total removal rate of CODcr registers 90% with im- proved biochemicality of the waste liquid. Finally, the paper concludes the proposed technique proves to be a feasible way for laboratory waste disposal.