广东化工
廣東化工
엄동화공
GUANGDONG CHEMICAL INDUSTRY
2012年
4期
161-162
,共2页
氯丁二烯%顶空-毛细管柱气相色谱%地表水
氯丁二烯%頂空-毛細管柱氣相色譜%地錶水
록정이희%정공-모세관주기상색보%지표수
chloroprene%headspace capillary GC%surface water
建立了顶空-毛细管柱-FID气相色谱检测地表水中氯丁二烯的方法。采用HP-INNOWAX色谱柱分离,优化了分流比及顶空条件,氯丁二烯在1～90μg/L的范围内获得了良好的线性关系（r=0.9994）,检出限（S/D=10）为0.01μg/L,地表水实际样品的加标回收率为98.5%～104.3%,相对标准偏差为2.45%。该方法操作简便、快速、灵敏度高,准确度和精密度均能满足检测要求,适用于地表水中氯丁二烯的检测。
建立瞭頂空-毛細管柱-FID氣相色譜檢測地錶水中氯丁二烯的方法。採用HP-INNOWAX色譜柱分離,優化瞭分流比及頂空條件,氯丁二烯在1～90μg/L的範圍內穫得瞭良好的線性關繫（r=0.9994）,檢齣限（S/D=10）為0.01μg/L,地錶水實際樣品的加標迴收率為98.5%～104.3%,相對標準偏差為2.45%。該方法操作簡便、快速、靈敏度高,準確度和精密度均能滿足檢測要求,適用于地錶水中氯丁二烯的檢測。
건립료정공-모세관주-FID기상색보검측지표수중록정이희적방법。채용HP-INNOWAX색보주분리,우화료분류비급정공조건,록정이희재1～90μg/L적범위내획득료량호적선성관계（r=0.9994）,검출한（S/D=10）위0.01μg/L,지표수실제양품적가표회수솔위98.5%～104.3%,상대표준편차위2.45%。해방법조작간편、쾌속、령민도고,준학도화정밀도균능만족검측요구,괄용우지표수중록정이희적검측。
A method of headspace capillary GC for determination of chloroprene in surface water was establish.Chloroprene was separated by HP-INNOWAX capillary column.With optimal shunt ratio,chloroprene showed a good linear range from 1～90 μg/L（r=0.9994）.The method detection limint（S/D=10） was 0.01 μg/L,recovery was in the range of 98.5 %～104.3 %,and RSD was 2.45 %.The established method is convenient,fast,sensitive and accurate,and can be used for determination of chloroprene in surface water.
