色谱
色譜
색보
CHINESE JOURNAL OF CHROMATOGRAPHY
2014年
9期
967-970
,共4页
同位素稀释法%高分辨气相色谱%高分辨质谱%二恶英类化合物%等价毒性当量%不确定度%土壤
同位素稀釋法%高分辨氣相色譜%高分辨質譜%二噁英類化閤物%等價毒性噹量%不確定度%土壤
동위소희석법%고분변기상색보%고분변질보%이악영류화합물%등개독성당량%불학정도%토양
isotope dilution method%high resolution gas chromatography (HRGC)%high resolution mass spectrometry (HRMS)%polychlorinated dibenzo-p-dioxins and dibenzofurans (PC-DD/Fs)%toxic equivalent quantity (TEQ)%uncertainty%soil
采用同位素稀释高分辨气相色谱-高分辨质谱法(isotope dilution high resolution gas chromatography and high resolution mass spectrometry,ID-HRGC-HRMS)测定土壤样品中二恶英类化合物(polychlorinated dibenzo-p-dioxins and dibenzofurans,PCDD/Fs)的等价毒性当量(toxic equivalent quantity,TEQ).讨论并确定了测定土壤样品中二恶英类化合物2,3,7,8位异构体不确定度的来源并合成了各异构体的相对标准不确定度;在此基础上,计算了3种等价毒性当量因子(toxic equivalent factor,TEF)框架下土壤样品中PCDD/Fs的TEQ浓度及其合成不确定度和扩展不确定度.
採用同位素稀釋高分辨氣相色譜-高分辨質譜法(isotope dilution high resolution gas chromatography and high resolution mass spectrometry,ID-HRGC-HRMS)測定土壤樣品中二噁英類化閤物(polychlorinated dibenzo-p-dioxins and dibenzofurans,PCDD/Fs)的等價毒性噹量(toxic equivalent quantity,TEQ).討論併確定瞭測定土壤樣品中二噁英類化閤物2,3,7,8位異構體不確定度的來源併閤成瞭各異構體的相對標準不確定度;在此基礎上,計算瞭3種等價毒性噹量因子(toxic equivalent factor,TEF)框架下土壤樣品中PCDD/Fs的TEQ濃度及其閤成不確定度和擴展不確定度.
채용동위소희석고분변기상색보-고분변질보법(isotope dilution high resolution gas chromatography and high resolution mass spectrometry,ID-HRGC-HRMS)측정토양양품중이악영류화합물(polychlorinated dibenzo-p-dioxins and dibenzofurans,PCDD/Fs)적등개독성당량(toxic equivalent quantity,TEQ).토론병학정료측정토양양품중이악영류화합물2,3,7,8위이구체불학정도적래원병합성료각이구체적상대표준불학정도;재차기출상,계산료3충등개독성당량인자(toxic equivalent factor,TEF)광가하토양양품중PCDD/Fs적TEQ농도급기합성불학정도화확전불학정도.
