CAJ | 학술논문

在DMF溶液中，采用高度稀释的方法，使二巯基马来二腈的二钠盐和2，3-Z-（碘乙氧乙氧乙硫基）-6，7-二取代四硫富瓦烯衍生物（化合物3）进行缩合反应，成功地合成了二氰基取代的大环硫杂冠醚并四硫富瓦烯衍生物。用^1HNMR，MS和IR表征了其结构，并用循环伏安法和紫外吸收光谱初步评价了衍生物的电化学性质和光物理性质。
재DMF용액중，채용고도희석적방법，사이구기마래이정적이납염화2，3-Z-（전을양을양을류기）-6，7-이취대사류부와희연생물（화합물3）진행축합반응，성공지합성료이청기취대적대배류잡관미병사류부와희연생물。용^1HNMR，MS화IR표정료기결구，병용순배복안법화자외흡수광보초보평개료연생물적전화학성질화광물이성질。
Under high dilution, condensation of disodium maleonitrile 2,3-dithiolate and compound 3 successfully synthesized the dicyano substituted thia crown ether annulated tetrathiafulvalene derivatives. Their structures were characterized by 1HNMR. MS and IR. The electrochemical and photophysical properties were evaluated via cyclic voltamtngrams and UV absorption spectrum.