环境科学与管理
環境科學與管理
배경과학여관리
ENVIRONMENTAL SCIENCE AND MANAGEMENT
2012年
9期
92-96
,共5页
刘从从%赵瑞红%王亚坤%徐明明%张晓帅
劉從從%趙瑞紅%王亞坤%徐明明%張曉帥
류종종%조서홍%왕아곤%서명명%장효수
SBA-15%电厂烟道气%C02%氨基化%吸附
SBA-15%電廠煙道氣%C02%氨基化%吸附
SBA-15%전엄연도기%C02%안기화%흡부
SBA - 15%flue gas from power plant%CO2%amino - functionalized%adsorption
文章以三嵌段共聚物P123为模板剂、正硅酸乙酯为硅源,水热合成了介孔分子筛SBA-15,以3-丙胺基三乙氧基硅烷(APTES)为氨基化剂,采用浸溃法将其嫁接到SBA-15孔内,形成氨基化的SBA-15用于吸附电厂尾气c02。通过氮等温吸附-脱附、XRD、TEM等测试技术对其进行了表征,考察了改性前后SBA-15的吸附性能。结果表明:改性前后的SBA-15对电厂尾气中CO:均具有良好的吸附性能,改性的SBA-15比合成的SBA-15吸附性能要好。
文章以三嵌段共聚物P123為模闆劑、正硅痠乙酯為硅源,水熱閤成瞭介孔分子篩SBA-15,以3-丙胺基三乙氧基硅烷(APTES)為氨基化劑,採用浸潰法將其嫁接到SBA-15孔內,形成氨基化的SBA-15用于吸附電廠尾氣c02。通過氮等溫吸附-脫附、XRD、TEM等測試技術對其進行瞭錶徵,攷察瞭改性前後SBA-15的吸附性能。結果錶明:改性前後的SBA-15對電廠尾氣中CO:均具有良好的吸附性能,改性的SBA-15比閤成的SBA-15吸附性能要好。
문장이삼감단공취물P123위모판제、정규산을지위규원,수열합성료개공분자사SBA-15,이3-병알기삼을양기규완(APTES)위안기화제,채용침궤법장기가접도SBA-15공내,형성안기화적SBA-15용우흡부전엄미기c02。통과담등온흡부-탈부、XRD、TEM등측시기술대기진행료표정,고찰료개성전후SBA-15적흡부성능。결과표명:개성전후적SBA-15대전엄미기중CO:균구유량호적흡부성능,개성적SBA-15비합성적SBA-15흡부성능요호。
Mesoporous molecular sieves SBA - 15 was synthesized by conventional hydrothermal process using tetraethylorthosilicate(TEOS)as silicon source and triblock copolymer P123 as template. CO2 sorbent were prepared by introducing(3 -Aminopropy) triethoxysilane (APTES) into SBA - 15 using a post - synthetic impregnation method. The synthesized sorbent was characterized by N2 adsorption - desorption, X - ray diffraction (XRD) and transmission electron microscopy ( TEM ). The adsorption properties of SBA - 15 and modified SBA - 15 were investigated under different and same temperatures. The results indicated that SBA - 15 and modified SBA - 15 both have a good adsorption performance, at the same temperature, the modified SBA - 15 shows better adsorption performance than the synthesis SBA - 15.