广州化工
廣州化工
엄주화공
GUANGZHOU CHEMICAL INDUSTRY AND TECHNOLOGY
2012年
17期
3-5
,共3页
喻淼%牛建兵%张果%牛静
喻淼%牛建兵%張果%牛靜
유묘%우건병%장과%우정
马来酰亚胺%生产废液%精馏%丙酮法
馬來酰亞胺%生產廢液%精餾%丙酮法
마래선아알%생산폐액%정류%병동법
bismaleimide%waste liquid%distillation%acetone method
利用丙酮法生产双马来酰亚胺树脂的过程中会产生大量工业废液,其主要成分为丙酮、水和醋酸,以及少量高沸点的树脂类聚合残余物。我们采用精馏的方法对双马来酰亚胺树脂产出废液进行处理,回收丙酮后,再回收其中的醋酸,同时利用酸碱滴定和高效液相色谱等方法对精馏液进行检测,发现这种方法处理得到的乙酸溶液浓度较高(20%),符合双马来酰亚胺树脂产出废液的综合、无害化处理的要求。
利用丙酮法生產雙馬來酰亞胺樹脂的過程中會產生大量工業廢液,其主要成分為丙酮、水和醋痠,以及少量高沸點的樹脂類聚閤殘餘物。我們採用精餾的方法對雙馬來酰亞胺樹脂產齣廢液進行處理,迴收丙酮後,再迴收其中的醋痠,同時利用痠堿滴定和高效液相色譜等方法對精餾液進行檢測,髮現這種方法處理得到的乙痠溶液濃度較高(20%),符閤雙馬來酰亞胺樹脂產齣廢液的綜閤、無害化處理的要求。
이용병동법생산쌍마래선아알수지적과정중회산생대량공업폐액,기주요성분위병동、수화작산,이급소량고비점적수지류취합잔여물。아문채용정류적방법대쌍마래선아알수지산출폐액진행처리,회수병동후,재회수기중적작산,동시이용산감적정화고효액상색보등방법대정류액진행검측,발현저충방법처리득도적을산용액농도교고(20%),부합쌍마래선아알수지산출폐액적종합、무해화처리적요구。
Large amount of waste liquid was produced from the produce process of bismaleimide resins with acetone method. The main components for this waste liquid were acetone, water, acetic acid and little polymerization resinic residue. Distillation was used to deal with waste liquid of bismaleimide resins, which was comprehensive and harmless treated for the recovery of acetone and acetic acid. Acid - base titration and High Performance Liquid Chromatography ( HPLC ) methods were also used to detect the distillation liquid. The results showed that the concentration (31.5%) of this acetic acid solution could meet industrial requirements.