北京科技大学学报
北京科技大學學報
북경과기대학학보
JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING
2013年
12期
1628-1635
,共8页
张坤%邢奕%洪晨%姜长禄%王志强%赵瑞雪
張坤%邢奕%洪晨%薑長祿%王誌彊%趙瑞雪
장곤%형혁%홍신%강장록%왕지강%조서설
废弃物利用%污泥%石灰干化%水泥%熟料%重金属
廢棄物利用%汙泥%石灰榦化%水泥%熟料%重金屬
폐기물이용%오니%석회간화%수니%숙료%중금속
waste utilization%sewage sludge%lime drying%cement%clinker%heavy metals
使用石灰干化污泥作为水泥原料的部分代替品制备水泥,石灰干化污泥质量分数变化范围在0~30%时探讨了石灰干化污泥的加入对水泥各项性能的影响.结果表明:石灰干化污泥以15%的加入量掺入生料后,可以明显改善水泥熟料的煅烧性能、矿物相晶体结构及形貌,并且能够显著增强水泥强度.当石灰干化污泥掺量继续增加后,其对于水泥性能的改善作用逐渐下降,当添加量达到30%时制得的水泥性能与未加入污泥的水泥已相差不大.毒性浸出实验结果显示:加入石灰干化污泥后,熟料和水泥的重金属含量较未加入污泥时高,但浸出量很低,浸出液中 Cu、Zn、Pb、Cr 和Ni的质量浓度均在1 mg·L-1以下,远低于国家标准GB 5085.3-2007,不会产生二次污染.
使用石灰榦化汙泥作為水泥原料的部分代替品製備水泥,石灰榦化汙泥質量分數變化範圍在0~30%時探討瞭石灰榦化汙泥的加入對水泥各項性能的影響.結果錶明:石灰榦化汙泥以15%的加入量摻入生料後,可以明顯改善水泥熟料的煅燒性能、礦物相晶體結構及形貌,併且能夠顯著增彊水泥彊度.噹石灰榦化汙泥摻量繼續增加後,其對于水泥性能的改善作用逐漸下降,噹添加量達到30%時製得的水泥性能與未加入汙泥的水泥已相差不大.毒性浸齣實驗結果顯示:加入石灰榦化汙泥後,熟料和水泥的重金屬含量較未加入汙泥時高,但浸齣量很低,浸齣液中 Cu、Zn、Pb、Cr 和Ni的質量濃度均在1 mg·L-1以下,遠低于國傢標準GB 5085.3-2007,不會產生二次汙染.
사용석회간화오니작위수니원료적부분대체품제비수니,석회간화오니질량분수변화범위재0~30%시탐토료석회간화오니적가입대수니각항성능적영향.결과표명:석회간화오니이15%적가입량참입생료후,가이명현개선수니숙료적단소성능、광물상정체결구급형모,병차능구현저증강수니강도.당석회간화오니참량계속증가후,기대우수니성능적개선작용축점하강,당첨가량체도30%시제득적수니성능여미가입오니적수니이상차불대.독성침출실험결과현시:가입석회간화오니후,숙료화수니적중금속함량교미가입오니시고,단침출량흔저,침출액중 Cu、Zn、Pb、Cr 화Ni적질량농도균재1 mg·L-1이하,원저우국가표준GB 5085.3-2007,불회산생이차오염.
Lime mediated sludge was used as partial replacement for cement raw materials to produce cement. The adding amount of lime mediated sludge ranges from 0 to 30%. The influence of lime mediated sludge on cement performance was investigated. It is shown that adding 15% of lime mediated sludge into cement raw materials can significantly improve the calcining performance, the mineral phase crystal structure and the clinker’s morphology, and the cement strength is also remarkably enhanced. The improvement capability of lime mediated sludge gradually declines with the increase of lime mediated sludge. When 30% of lime mediated sludge is added, the properties of the obtained cement are similar to those without adding sludge. Toxicity characteristic leaching test results indicate that after lime mediated sludge addition, heavy metal concentrations in clinker and cement are higher than those in clinker and cement without lime mediated sludge, while the leaching concentrations are very low, Cu, Zn, Pb, Cr and Ni contents in the leachate are all below 1 mg·L-1, which can meet the People’s Republic of China Standard GB 5085.3-2007, with no risks of secondary pollution.