石油与天然气化工
石油與天然氣化工
석유여천연기화공
CHEMICAL ENGINEERING OF OIL AND GAS
2013年
6期
637-641
,共5页
极性四组分%偶极矩%稠油黏度%乳状液%反相点
極性四組分%偶極矩%稠油黏度%乳狀液%反相點
겁성사조분%우겁구%주유점도%유상액%반상점
polar fractions%dipole moments%viscosity of heavy oil%emulsion%reverse phase point
采用灰色关联熵分析法研究了胜利油田稠油黏度与其极性四组分含量和极性组分偶极矩的关联。同时通过改变实验油样乳状液的含水率及温度,探究了稠油组成性质与其乳状液反相点的关联。结果表明:稠油极性四组分含量与其黏度关联度的顺序是:沥青质>胶质>芳香分>饱和分;稠油极性组分偶极矩与其黏度的关联度顺序是:沥青质>胶质>芳香分。随着稠油胶质、沥青质含量的增大,油水界面张力的降低、油滴Zeta电位绝对值的增大,乳状液含水率的反相点及温度的反相点逐渐升高。
採用灰色關聯熵分析法研究瞭勝利油田稠油黏度與其極性四組分含量和極性組分偶極矩的關聯。同時通過改變實驗油樣乳狀液的含水率及溫度,探究瞭稠油組成性質與其乳狀液反相點的關聯。結果錶明:稠油極性四組分含量與其黏度關聯度的順序是:瀝青質>膠質>芳香分>飽和分;稠油極性組分偶極矩與其黏度的關聯度順序是:瀝青質>膠質>芳香分。隨著稠油膠質、瀝青質含量的增大,油水界麵張力的降低、油滴Zeta電位絕對值的增大,乳狀液含水率的反相點及溫度的反相點逐漸升高。
채용회색관련적분석법연구료성리유전주유점도여기겁성사조분함량화겁성조분우겁구적관련。동시통과개변실험유양유상액적함수솔급온도,탐구료주유조성성질여기유상액반상점적관련。결과표명:주유겁성사조분함량여기점도관련도적순서시:력청질>효질>방향분>포화분;주유겁성조분우겁구여기점도적관련도순서시:력청질>효질>방향분。수착주유효질、력청질함량적증대,유수계면장력적강저、유적Zeta전위절대치적증대,유상액함수솔적반상점급온도적반상점축점승고。
The correlation between the contents and properties of polar fractions and the vis-cosity of heavy oil were studied by gray correlation entropy method .By changing volume fraction of water and temperature of the emulsions of heavy oil ,the relation between the composition property of heavy oil and the reverse phase point were also researched .The result showed that the order of correlation degree between the polar fractions and the viscosity of heavy oil was :as-phaltene>resin>aromatic>saturate;and the order of correlation degree between the mean dipo-lemoments of polar fractions and the viscosity of heavy oil was :asphaltene>resin>aromatic .In addition ,as the increase of the contents of the resin and asphaltene ,the decrease of the interfacial tension of oil-water ,and the increase of Zeta absolute value of oil drops ,the volume fraction of water and temperature at the reverse phase point of emulsion gradually raised .