CAJ | 학술논문

在400K温度下，通过溶剂热合成方法，以Co(CH3COO)2?4H2O，Sn粉，S粉为原料，按化学反应计量比混合，二乙烯三胺和水为溶剂反应合成了一个新的硫属化合物[Co(dien)2][Sn2S6].通过元素分析和X-射线单晶衍射仪对此化合物结构进行表征，化合物属三斜晶系，空间群为P-1.该化合物包含四面体形状的[Sn2S6]4-阴离子和过渡金属配合物阳离子[Co(dien)2]2+.这两种结构单元通过氢键相连形成三维网状结构.
재400K온도하，통과용제열합성방법，이Co(CH3COO)2?4H2O，Sn분，S분위원료，안화학반응계량비혼합，이을희삼알화수위용제반응합성료일개신적류속화합물[Co(dien)2][Sn2S6].통과원소분석화X-사선단정연사의대차화합물결구진행표정，화합물속삼사정계，공간군위P-1.해화합물포함사면체형상적[Sn2S6]4-음리자화과도금속배합물양리자[Co(dien)2]2+.저량충결구단원통과경건상련형성삼유망상결구.
A new transition metal selenidoantimonates, [Co(dien)][Sn2S6] (dien = diethylenetriamine), have been synthesized by solvothermal reacting of Co(CH3COO)2?4H2O, Sn and S in a stoichiometric ratio in ethanolamine solution at 400 K. The structure was characterized by elemental analysis and single-crystal X-ray diffraction. The compound crystallizes in the triclinic space group P-1. The structure consists of tetrahedral [Sn2S6]2-anion and transition metal complex [Co(dien)2]2+cation. These three types of units are interlinked via various hydrogen-bonding interactions to from a three-dimensional (3D) network.