CAJ | 학술논문

β-环糊精(β-CD)作为淀粉的衍生物,具有天然、无毒、环保、价格低廉等优点,越来越受到研究者的关注。采用马来酸酐(MA H )对β-CD 进行改性,得到可聚合单体(β-CD-MAH),采用过硫酸铵(APS)/亚硫酸氢钠(SBS)氧化-还原体系引发单体3-(4’-乙烯基苄基)-5,5-二甲基海因(缩写为 VBDMH )与其共聚,成功制备β-CD基卤胺化合物抗菌共聚物(缩写为β-CD-MAH-VBDMH),并采用固体13 C 核磁和红外光谱图表征了其化学结构。将抗菌剂β-CD-MAH-VBDMH和乙酸纤维素(CA)混合,利用静电纺丝技术,制备具有抗菌功能的纳米纤维,并采用SEM对纳米纤维进行了表征,确定静电纺丝的最佳工艺。碘量滴定法滴定的最佳工艺条件下纳米纤维的氯含量表明,所制得的纳米纤维具有很好的抗菌性能。
β-배호정(β-CD)작위정분적연생물,구유천연、무독、배보、개격저렴등우점,월래월수도연구자적관주。채용마래산항(MA H )대β-CD 진행개성,득도가취합단체(β-CD-MAH),채용과류산안(APS)/아류산경납(SBS)양화-환원체계인발단체3-(4’-을희기변기)-5,5-이갑기해인(축사위 VBDMH )여기공취,성공제비β-CD기서알화합물항균공취물(축사위β-CD-MAH-VBDMH),병채용고체13 C 핵자화홍외광보도표정료기화학결구。장항균제β-CD-MAH-VBDMH화을산섬유소(CA)혼합,이용정전방사기술,제비구유항균공능적납미섬유,병채용SEM대납미섬유진행료표정,학정정전방사적최가공예。전량적정법적정적최가공예조건하납미섬유적록함량표명,소제득적납미섬유구유흔호적항균성능。
As one of starch derivatives,β-cyclodextrin (β-CD)has received more and more attentions due to its excellent properties,such as rechargeable,biodegradable,low price,etc.In this work,a polymerizable mono-mer (β-CD-MAH)was obtained by using maleic anhydride (MAH)reacted with theβ-CD.Antimicrobial poly-merβ-CD-MAH-VBDMH was synthesized by the reaction betweenβ-CD-MAH and 3-(4′-vinylbenzyl)-5,5-dim-ethylhydantoin (VBDMH)using ammonium persulfate (APS)/sodium bisulfite (SBS)oxidation-reduction sys-tem as initiator,and characterized by solid-state 13 C NMR and FT-IR.The electrospun nanofibers were obtained by mixing solution of the synthesized antibacterial polymerβ-CD-MAH-VBDMH and cellulose acetate (CA). The optimum condition was determined by SEM.The chlorine content of the chlorinated nanofibers under the optimum condition was determined by iodometric titration,which indicated that the chlorinated nanofibers would have good antibacterial property.