沈阳大学学报:自然科学版
瀋暘大學學報:自然科學版
침양대학학보:자연과학판
Journal of Shenyang University
2012年
5期
15-18
,共4页
钼氧酸盐%锌配合物%单晶结构%水热合成
鉬氧痠鹽%鋅配閤物%單晶結構%水熱閤成
목양산염%자배합물%단정결구%수열합성
molybdate%Zn Complex%single crystal Structure%hydrothermal synthesis
利用水热合成法得到了含有类梯形钼氧酸盐阴离子片段且具有二维层状结构的配合物[Zn(bpy)Mo3O10]1.通过X射线衍射确定晶体结构,应用元素分析、红外光谱、热重分析对晶体进行了表征.结果表明,构筑配合物的{Mo3O10}2-阴离子呈一维带状结构,由{MoO6}八面体、{MoO5}四方锥和{MoO4}四面体三种钼氧单元共同构成,并通过{Zn(bpy)}2+基团连接成二维层状结构.
利用水熱閤成法得到瞭含有類梯形鉬氧痠鹽陰離子片段且具有二維層狀結構的配閤物[Zn(bpy)Mo3O10]1.通過X射線衍射確定晶體結構,應用元素分析、紅外光譜、熱重分析對晶體進行瞭錶徵.結果錶明,構築配閤物的{Mo3O10}2-陰離子呈一維帶狀結構,由{MoO6}八麵體、{MoO5}四方錐和{MoO4}四麵體三種鉬氧單元共同構成,併通過{Zn(bpy)}2+基糰連接成二維層狀結構.
이용수열합성법득도료함유류제형목양산염음리자편단차구유이유층상결구적배합물[Zn(bpy)Mo3O10]1.통과X사선연사학정정체결구,응용원소분석、홍외광보、열중분석대정체진행료표정.결과표명,구축배합물적{Mo3O10}2-음리자정일유대상결구,유{MoO6}팔면체、{MoO5}사방추화{MoO4}사면체삼충목양단원공동구성,병통과{Zn(bpy)}2+기단련접성이유층상결구.
A new layered complex [Zn(bpy)Mo3O10] 1 containing ladder-like molybdenium oxide anion clusters was synthesized under hydrothermal conditions.It was determined structurally by X-ray single crystal diffraction and characterized by elemental analysis,IR spectroscopy and TG analysis.The supporting {Mo3O10}2-anion exhibits an infinite 1D ribbon structure and constructed by {MOO6} Octahedra,{MOO5} square pyramid and{MOO4} tetrehedra,and then the ribbons were connected through {Zn(bpy)}2+ fragments into a 2D layer structure.