功能材料
功能材料
공능재료
JOURNAL OF FUNCTIONAL MATERIALS
2013年
24期
3581-3586
,共6页
陈婉玲%彭亦如%贺丹丹%马冬冬%张甜甜%魏珍珍%吴雪蓉
陳婉玲%彭亦如%賀丹丹%馬鼕鼕%張甜甜%魏珍珍%吳雪蓉
진완령%팽역여%하단단%마동동%장첨첨%위진진%오설용
酞菁锌(Ⅱ)%树枝配体%表面活性剂%聚合物纳米胶束
酞菁鋅(Ⅱ)%樹枝配體%錶麵活性劑%聚閤物納米膠束
태정자(Ⅱ)%수지배체%표면활성제%취합물납미효속
phthalocyanine zinc(Ⅱ)%dendrimer%surfactants%polymer nanomicelle
通过紫外光谱法和荧光光谱法比较,研究了阳离子表面活性剂十六烷基三甲基溴化铵(CTAB)对0~2代以羧基为端基的芳基苄醚树枝配体取代酞菁锌(Ⅱ)配合物(ZnPc(COOH)4、G1-ZnPc(COOH)8和G2-ZnPc (COOH )16)聚集行为的影响。ZnPc (COOH)4、G1-ZnPc(COOH)8和 G2-ZnPc(COOH)16在水溶液中主要以二聚体形式存在。加入 CTAB 后, ZnPc (COOH )4、G1-ZnPc (COOH )8和 G2-ZnPc (COOH)16的单体吸收峰强度均增强,二聚体吸收峰强度均逐渐减弱;荧光光谱均明显增强,这表明 CTAB对树枝酞菁体系具有明显的解聚作用。这是因为 Zn-Pc (COOH )4、G1-ZnPc (COOH )8和 G2-ZnPc (COOH)16表面带负电荷的羧基与带正电荷的 CTAB通过静电作用形成纳米胶束,破坏了羧基酞菁聚集体之间的氢键。通过Zetasize粒度分析仪研究了不同浓度的CTAB与羧基酞菁形成纳米胶束的粒径分布情况,平均粒径范围约在5~30 nm,并随着 CTAB 浓度的增加,纳米胶束的平均粒径增大;随着树枝代数增加,纳米胶束的平均粒径逐渐减小。因此,阳离子表面活性剂CTAB可以有效抑制酞菁在水溶液中的聚集行为,在开展酞菁的光化学和物理研究方面具有很好的应用前景。
通過紫外光譜法和熒光光譜法比較,研究瞭暘離子錶麵活性劑十六烷基三甲基溴化銨(CTAB)對0~2代以羧基為耑基的芳基芐醚樹枝配體取代酞菁鋅(Ⅱ)配閤物(ZnPc(COOH)4、G1-ZnPc(COOH)8和G2-ZnPc (COOH )16)聚集行為的影響。ZnPc (COOH)4、G1-ZnPc(COOH)8和 G2-ZnPc(COOH)16在水溶液中主要以二聚體形式存在。加入 CTAB 後, ZnPc (COOH )4、G1-ZnPc (COOH )8和 G2-ZnPc (COOH)16的單體吸收峰彊度均增彊,二聚體吸收峰彊度均逐漸減弱;熒光光譜均明顯增彊,這錶明 CTAB對樹枝酞菁體繫具有明顯的解聚作用。這是因為 Zn-Pc (COOH )4、G1-ZnPc (COOH )8和 G2-ZnPc (COOH)16錶麵帶負電荷的羧基與帶正電荷的 CTAB通過靜電作用形成納米膠束,破壞瞭羧基酞菁聚集體之間的氫鍵。通過Zetasize粒度分析儀研究瞭不同濃度的CTAB與羧基酞菁形成納米膠束的粒徑分佈情況,平均粒徑範圍約在5~30 nm,併隨著 CTAB 濃度的增加,納米膠束的平均粒徑增大;隨著樹枝代數增加,納米膠束的平均粒徑逐漸減小。因此,暘離子錶麵活性劑CTAB可以有效抑製酞菁在水溶液中的聚集行為,在開展酞菁的光化學和物理研究方麵具有很好的應用前景。
통과자외광보법화형광광보법비교,연구료양리자표면활성제십륙완기삼갑기추화안(CTAB)대0~2대이최기위단기적방기변미수지배체취대태정자(Ⅱ)배합물(ZnPc(COOH)4、G1-ZnPc(COOH)8화G2-ZnPc (COOH )16)취집행위적영향。ZnPc (COOH)4、G1-ZnPc(COOH)8화 G2-ZnPc(COOH)16재수용액중주요이이취체형식존재。가입 CTAB 후, ZnPc (COOH )4、G1-ZnPc (COOH )8화 G2-ZnPc (COOH)16적단체흡수봉강도균증강,이취체흡수봉강도균축점감약;형광광보균명현증강,저표명 CTAB대수지태정체계구유명현적해취작용。저시인위 Zn-Pc (COOH )4、G1-ZnPc (COOH )8화 G2-ZnPc (COOH)16표면대부전하적최기여대정전하적 CTAB통과정전작용형성납미효속,파배료최기태정취집체지간적경건。통과Zetasize립도분석의연구료불동농도적CTAB여최기태정형성납미효속적립경분포정황,평균립경범위약재5~30 nm,병수착 CTAB 농도적증가,납미효속적평균립경증대;수착수지대수증가,납미효속적평균립경축점감소。인차,양리자표면활성제CTAB가이유효억제태정재수용액중적취집행위,재개전태정적광화학화물리연구방면구유흔호적응용전경。
The interaction between the phthalocyanine zinc(Ⅱ)bearing poly(aryl benzyl ether)dendritic substit-uents with carboxylic terminal (ZnPc(COOH)4 ,G1-ZnPc(COOH)8 and G2-ZnPc(COOH)16 )and cationic sur-factants(cetyltrimethyl ammonium bromide(CTAB))were studied by fluorescence and UV-Vis spectroscopic methods.ZnPc(COOH)4 ,G1-ZnPc(COOH)8 and G2-ZnPc(COOH)16 mainly existed as a dimer at 625 nm in aqueous media,but they mainly exhibited as monomers at 685 nm with addition of CTAB.As the concentra-tion of CTAB increased,the intensity of the monomeric absorption peak increased,while that of the dimer peaks decreased gradually.Meanwhile,the fluorescence intensity of ZnPc(COOH)4 ,G1-ZnPc(COOH)8 and G2-ZnPc(COOH)16 also markedly enhanced.Therefore,the aggregation behavior of these water-soluble den-dritic phthalocyanines could be disrupted effectively by addition of CTAB.The electrostatic interaction between the positive charges of the CTAB and negative charges of the dendritic phthalocyanine leaded to dis-aggregation of the dendritic phthalocyanine.The nanoparticles were formed by encapsulation of water-soluble dendritic phthalocyanines into the CTAB micelles.The diameters of nanoparticles were studied by Zetasize particle size analyzer.The average sizes of nano-particles were in the range of 5-30 nm.The size of nano-particles increased with the increasing the concentration of CTAB while decreasing with increasing of the dendritic generation. This would provide a useful method for solving the aggregation problem associated with phthalocyanine,and showed potential application in various photophysical and chemical applications.