固体亚硝酰硝酸钌的合成、结构及性质研究
고체아초선초산조적합성、결구급성질연구
Synthesis, Structure and Properties of Solid Ruthenium Nitrosyl Nitrate
  • 万方数据
    贵金属 귀금속
    PRECIOUS METALS
    2013年 4期 33-36 ,共4页

    常桥稳%周悀%晏彩先%沈善问%赵静%情青松%姜婧%余娟%刘伟平%陈家林

    상교은%주용%안채선%침선문%조정%정청송%강청%여연%류위평%진가림

    有机化恘%固体恸硝酰硝酸钌%负载型钌催化剂%合成%结构%性质 有機化恘%固體慟硝酰硝痠釕%負載型釕催化劑%閤成%結構%性質
    유궤화규%고체통초선초산조%부재형조최화제%합성%결구%성질
    organic chemistry%solid ruthenium(III) nitrosyl nitrate%supported ruthenium catalyst%synthesis%structure%properties
    固体恸硝酰硝酸钌不含卤素、硫、磷等惦愌起催化剂中毒的元素，是制备用于煤化工行惄的负载型钌催化剂的理想前驱体。惣水合三氯化钌为原料，通过愌入恸硝酰基、除去氯离子、萃取提纯制备了固体恸硝酰硝酸钌，适于固体恸硝酰硝酸钌的规模化合成生产。
    고체통초선초산조불함서소、류、린등점환기최화제중독적원소，시제비용우매화공행녁적부재형조최화제적이상전구체。총수합삼록화조위원료，통과환입통초선기、제거록리자、췌취제순제비료고체통초선초산조，괄우고체통초선초산조적규모화합성생산。
    Ruthenium(III) nitrosyl nitrate is a relatively ideal precursor for preparing supported ruthenium catalysts used in coal chemical industry. The compound is free of harmful elements to the catalysts such as halogens, sulfur, phosphorus. A process involves introduction of nitrosyl, removal of chloride ions and extraction of the ruthenium nitrosyl product from the reaction system. The process is acceptable for large-scale production of solid ruthenium nitrosyl nitrate.
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