湖南工业大学学报
湖南工業大學學報
호남공업대학학보
JOURNAL OF HUNAN UNIVERSITY OF TECHNOLOGY
2012年
3期
25-28
,共4页
苯乙烯%β-环糊精%无皂乳液聚合%聚苯乙烯
苯乙烯%β-環糊精%無皂乳液聚閤%聚苯乙烯
분을희%β-배호정%무조유액취합%취분을희
styrene%β-cyclodextrin%soap-free emulsion polymerization%polystyrene
选用β-环糊精为稳定剂,以苯乙烯为原料、过硫酸钾为引发剂,采用无皂乳液聚合法制备单分散聚苯乙烯微球。利用扫描电镜对微球进行表征,研究了微球合成过程中稳定剂用量、苯乙烯单体用量及引发剂用量对微球粒径分布的影响。实验结果表明:适当地改变稳定剂用量、苯乙烯单体用量及引发剂用量可以得到不同粒径且单分散性良好的聚苯乙烯微球。
選用β-環糊精為穩定劑,以苯乙烯為原料、過硫痠鉀為引髮劑,採用無皂乳液聚閤法製備單分散聚苯乙烯微毬。利用掃描電鏡對微毬進行錶徵,研究瞭微毬閤成過程中穩定劑用量、苯乙烯單體用量及引髮劑用量對微毬粒徑分佈的影響。實驗結果錶明:適噹地改變穩定劑用量、苯乙烯單體用量及引髮劑用量可以得到不同粒徑且單分散性良好的聚苯乙烯微毬。
선용β-배호정위은정제,이분을희위원료、과류산갑위인발제,채용무조유액취합법제비단분산취분을희미구。이용소묘전경대미구진행표정,연구료미구합성과정중은정제용량、분을희단체용량급인발제용량대미구립경분포적영향。실험결과표명:괄당지개변은정제용량、분을희단체용량급인발제용량가이득도불동립경차단분산성량호적취분을희미구。
Using styrene as raw material,potassium persulfate as an initiator and β-cyclodextrin as a stabilizer,polystyrene microspheres were successfully prepared by means of soap-free emulsion polymerization method.The microstructures were characterized with SEM,and the effects of the stabilizer dosage,the styrene monomer dosage and initiator dosage on the particle size distribution were studied.The results show that polystyrene microspheres with different particle sizes and good monodispersity were obtained by changing amount of stabilizer and the styrene monomer dosage and dosage of initiator appropriately.