新疆大学学报(自然科学版)
新疆大學學報(自然科學版)
신강대학학보(자연과학판)
XINJIANG UNIVERSITY JOURNAL(NATURAL SCIENCE EDITION)
2013年
3期
339-343
,共5页
张月%王丰%吕帅%关晓梅
張月%王豐%呂帥%關曉梅
장월%왕봉%려수%관효매
凹凸黏土%汞离子%动力学%吸附
凹凸黏土%汞離子%動力學%吸附
요철점토%홍리자%동역학%흡부
attapulgite%mercury%adsorption%kinetics
研究了凹凸棒黏土对溶液中汞(Ⅱ)的吸附行为,考察了凹凸棒的细度溶液pH值、吸附时间、吸附温度等条件对凹凸棒吸附汞的吸附率的影响;分析凹凸棒对汞的吸附动力学和热力学行为。结果表明:凹凸棒石黏土对溶液中的汞离子具有较好的吸附,降低凹凸棒黏土细度有利于提高吸附率。温度在40?C左右,吸附时间40 min pH值7以上,吸附率可达90%以上,吸附容量454 mg/g 。吸附符合准二级动力学方程和Freundlich型吸附等温线,属于化学吸附。
研究瞭凹凸棒黏土對溶液中汞(Ⅱ)的吸附行為,攷察瞭凹凸棒的細度溶液pH值、吸附時間、吸附溫度等條件對凹凸棒吸附汞的吸附率的影響;分析凹凸棒對汞的吸附動力學和熱力學行為。結果錶明:凹凸棒石黏土對溶液中的汞離子具有較好的吸附,降低凹凸棒黏土細度有利于提高吸附率。溫度在40?C左右,吸附時間40 min pH值7以上,吸附率可達90%以上,吸附容量454 mg/g 。吸附符閤準二級動力學方程和Freundlich型吸附等溫線,屬于化學吸附。
연구료요철봉점토대용액중홍(Ⅱ)적흡부행위,고찰료요철봉적세도용액pH치、흡부시간、흡부온도등조건대요철봉흡부홍적흡부솔적영향;분석요철봉대홍적흡부동역학화열역학행위。결과표명:요철봉석점토대용액중적홍리자구유교호적흡부,강저요철봉점토세도유리우제고흡부솔。온도재40?C좌우,흡부시간40 min pH치7이상,흡부솔가체90%이상,흡부용량454 mg/g 。흡부부합준이급동역학방정화Freundlich형흡부등온선,속우화학흡부。
The adsorption of the attapulgite for mercury in aqueous was studied. Various factors affecting adsorption such as pH values, adsorption time, and adsorption temperature were investigated and the ad-sorption kinetics were also explored. The results show that attapulgite has absorbability for Hg(Ⅱ) aqueous, absorption rate was increased when decreasing the attapulgite particle size. And absorption rate exceeded 90% at the conditions of temperature about 40?C, time 40min, pH 7. Capacity of the absorption reached 454mg/g. The kinetics of adsorption followed pseudo-second-order model and the equilibrium data were well fitted to the Freundlich. The absorption was chemical absorption.