CAJ | 학술논문

采用共沉淀法合成Mg/Al摩尔比为2：1的层状双金属氢氧化物Mg/Al-LDH，并在500°C下煅烧6 h得到煅烧双金属氢氧化物Mg/Al-CLDH。研究Mg/Al-CLDH对钒酸根的吸附性能，探讨镁铝摩尔比、吸附剂用量、溶液初始浓度、时间和温度等因素对吸附效果的影响，并对其吸附过程的动力学和热力学过程进行研究。研究表明：Mg/Al-CLDH 对钒酸根的吸附效果很好。该吸附过程符合准一级动力学方程，平衡吸附等温线很好地符合Langmuir方程，并且Langmuir方程拟合常数高达0.999。通过热力学计算发现ΔGΘ为负值，ΔHΘ为正值，表明此吸附本质上是吸热自发过程。吸附机理研究表明此吸附主要是表面吸附。
채용공침정법합성Mg/Al마이비위2：1적층상쌍금속경양화물Mg/Al-LDH，병재500°C하단소6 h득도단소쌍금속경양화물Mg/Al-CLDH。연구Mg/Al-CLDH대범산근적흡부성능，탐토미려마이비、흡부제용량、용액초시농도、시간화온도등인소대흡부효과적영향，병대기흡부과정적동역학화열역학과정진행연구。연구표명：Mg/Al-CLDH 대범산근적흡부효과흔호。해흡부과정부합준일급동역학방정，평형흡부등온선흔호지부합Langmuir방정，병차Langmuir방정의합상수고체0.999。통과열역학계산발현ΔGΘ위부치，ΔHΘ위정치，표명차흡부본질상시흡열자발과정。흡부궤리연구표명차흡부주요시표면흡부。
Mg/Al-CO3 layered double hydroxide (LDH2) with Mg(II):Al(III) molar ratio of 2:1 was synthesized by co-precipitation method and its calcined product Mg2Al-CLDH(CLDH2) was prepared by heating Mg2Al-LDH at 773 K for 6 h. Removal of vanadate anion ( 3-4VO ) from aqueous solution on CLDH2 was studied. Batch studies were carried out to address various experimental parameters such as Mg/Al molar ratio, adsorbent dosage, initial concentration of solution, contact time and temperature. Vanadate was removed effectively at the optimized experimental conditions. The adsorption kinetics data fitted the pseudo-first-order model. Isotherms for adsorption vanadate by CLDH2 at different solution temperatures were well described using the Langmuir and Freundlich equations, and the isotherm parameters were calculated using linear regression analysis. The adsorption data fitted the langmuir model with good values of the correlation coefficient (R2>0.999). The negative value ofΔGΘand the positive value ofΔHΘindicate that the adsorption processes are spontaneous endothermic in nature. The mechanism of adsorption suggests that the surface adsorption is the main process.