有色金属科学与工程
有色金屬科學與工程
유색금속과학여공정
JIANGXI NONFERROUS METALS
2014年
3期
81-85,106
,共6页
陈明%蔡忠萍%熊琳媛%蔡青云%徐慧
陳明%蔡忠萍%熊琳媛%蔡青雲%徐慧
진명%채충평%웅림원%채청운%서혜
矿山酸性废水%锌回收%电位调控-硫化沉淀
礦山痠性廢水%鋅迴收%電位調控-硫化沉澱
광산산성폐수%자회수%전위조공-류화침정
mine acid drainage%zinc recovery%potential regulation-sulfide precipitation
采用电位调控-硫化沉淀法对含Zn2+100 mg/L的矿山酸性废水进行深度处理.结果表明,采用10%石灰乳液为中和药剂预先除铁,其用量为7.5~14 mL/L,沉铁时间为30 min,铁的去除率可以达到80%以上;除铁后的溶液采用硫化法沉淀锌,以NaHS为硫化剂,pH值为3.4,PAM用量为1 mL/L,氧化还原电位控制在6~76 mV时,矿山酸性废水中的Zn2+的去除率达到96.85%以上.
採用電位調控-硫化沉澱法對含Zn2+100 mg/L的礦山痠性廢水進行深度處理.結果錶明,採用10%石灰乳液為中和藥劑預先除鐵,其用量為7.5~14 mL/L,沉鐵時間為30 min,鐵的去除率可以達到80%以上;除鐵後的溶液採用硫化法沉澱鋅,以NaHS為硫化劑,pH值為3.4,PAM用量為1 mL/L,氧化還原電位控製在6~76 mV時,礦山痠性廢水中的Zn2+的去除率達到96.85%以上.
채용전위조공-류화침정법대함Zn2+100 mg/L적광산산성폐수진행심도처리.결과표명,채용10%석회유액위중화약제예선제철,기용량위7.5~14 mL/L,침철시간위30 min,철적거제솔가이체도80%이상;제철후적용액채용류화법침정자,이NaHS위류화제,pH치위3.4,PAM용량위1 mL/L,양화환원전위공제재6~76 mV시,광산산성폐수중적Zn2+적거제솔체도96.85%이상.
Potential regulation-sulfide precipitation are used to treat zinc-containing mine acid drainage with the concentration of 100mg/L deeply. When 10 % CaO is selected as a neutralizing agent to remove iron, (the amount of 10 % CaO 7.5~14 ml/L, precipitation time of iron 30 min), the removal rate of iron could reach above 80 %. Vulcanization is performed on the de-ironed solution to precipitate zinc using NaHS as the vulcanizing agent, (with the sulfide precipitation zinc pH value of 3.4, the dosing quantity of PAM flocculant of 1mL/L, and ORP of at 6~76 mV), the removal rate of zinc ions in acid drainage can be over 96.85 %.