CAJ | 학술논문

以钨酸钠和盐酸为原料，碳纳米管为载体，采用一步法将钨酸颗粒直接沉积在碳纳米管管壁上，形成钨酸-碳纳米管（H2WO4-CNTs）复合物.或采用二步法将钨酸沉淀与碳纳米管复合，形成H2WO4-CNTs复合物.之后，在氧气气氛下进行煅烧，生成了氧化钨粉末.经物理性能测试，2种方法制备的H2WO4-CNTs复合物中钨酸颗粒的平均粒径分别为10 nm和100 nm.氧化钨粉末的平均粒径分别为250 nm和2μm，比表面积分别为36.53 m2/g和13.99 m2/g.采用紫外可见分光光度计测定了氧化钨的光催化性能，在11 W的日光灯照射下，当光照时间为30 min时，脱色率分别达到93.8%和79.1%.结果表明，一步法制备的氧化钨因具有更小的平均粒径和更大的比表面积，表现出更好的物理吸附性能和光催化性能.
이오산납화염산위원료，탄납미관위재체，채용일보법장오산과립직접침적재탄납미관관벽상，형성오산-탄납미관（H2WO4-CNTs）복합물.혹채용이보법장오산침정여탄납미관복합，형성H2WO4-CNTs복합물.지후，재양기기분하진행단소，생성료양화오분말.경물이성능측시，2충방법제비적H2WO4-CNTs복합물중오산과립적평균립경분별위10 nm화100 nm.양화오분말적평균립경분별위250 nm화2μm，비표면적분별위36.53 m2/g화13.99 m2/g.채용자외가견분광광도계측정료양화오적광최화성능，재11 W적일광등조사하，당광조시간위30 min시，탈색솔분별체도93.8%화79.1%.결과표명，일보법제비적양화오인구유경소적평균립경화경대적비표면적，표현출경호적물리흡부성능화광최화성능.
s: Sodium tungstate and hydrochloric acid are used as raw materials, carbon nanotubes as tem-plate, tungsten acid and carbon nanotube composite are prepared respectively by using one-step and two-step method, and then roasted at 600 ℃ for 2 h under oxygen atmosphere. The average particle size of tung-sten acid and carbon nanotubes composite prepared one and two step methods are 10 nm and 100 nm re-spectively. The average particle size of tungsten oxide powders are 250 nm and 2 μm respectively. The spe-cific surface area of tungsten oxide powders is 36.53 m2/g and 13.99 m2/g respectively. The photocatalytic performance of tungsten oxide is studied by the UV-Vis spectrophotometer using 11W fluorescent light as the light source. The degradation rate of tungsten oxide powders can reach 93.8 % and 79.1 %. The physical ab-sorption and photocatalytic activity of tungsten oxide prepared by one-step method is better than that of two-step method because of its smaller particle diameter and higher specific surface area.