CAJ | 학술논문

在400K温度下，以HgCl2，Sb粉和S粉为原料，将其按化学计量比进行混合，在二乙烯三胺和水混合溶剂的条件下，通过溶剂热合成方法反应得到了一个新的硫属化合物[dienH2]Hg2Sb2S6.通过元素分析和X-射线单晶衍射仪对此化合物进行结构表征，该晶体属于正交晶系，空间群为Cmca.该化合物由二维层状的[Hg2Sb2S6]2-阴离子和质子化的[dienH2]2+阳离子组成，两种结构通过氢键相互连接形成二维层状结构.
재400K온도하，이HgCl2，Sb분화S분위원료，장기안화학계량비진행혼합，재이을희삼알화수혼합용제적조건하，통과용제열합성방법반응득도료일개신적류속화합물[dienH2]Hg2Sb2S6.통과원소분석화X-사선단정연사의대차화합물진행결구표정，해정체속우정교정계，공간군위Cmca.해화합물유이유층상적[Hg2Sb2S6]2-음리자화질자화적[dienH2]2+양리자조성，량충결구통과경건상호련접형성이유층상결구.
A new transition metal complex directedmercury thioantimonate, [dienH2]Hg2Sb2S6(dien = diethylenetriamine), has been synthesized by solvothermal reaction of HgCl2, Sb and S in diethylenetriamine solution at 400 K. The crystal structure was characterized by elemental analysis and single-crystal X-ray diffraction. The title compound crystallizes in the orthorhombic system (Cmca). The structure consists of two-dimensional (2D) [Hg2Sb2S6]2 -layer and protonated diethylenetriamine cation[dienH2]2+. These two types of units are interlinked via various hydrogen-bonding interactions to from a two-dimensional (3D) framework.