环境监控与预警
環境鑑控與預警
배경감공여예경
ENVIRONMENTAL MONITORING AND FOREWARNING
2014年
3期
20-23
,共4页
重金属%快速监测%比色法%阳极溶出伏安法
重金屬%快速鑑測%比色法%暘極溶齣伏安法
중금속%쾌속감측%비색법%양겁용출복안법
Heavy metals%Rapid monitoring%Colorimentric method%ASV
在国内外重金属监测技术的基础上对环境污染事故中重金属(铜、铅、锌、砷、汞、铬、镉)的两种主要快速监测方法进行了研究。研究结果表明:比色法可测试铜、铅、锌、镉、六价铬5种重金属,且精密度与准确度均较好;阳极溶出伏安法(ASV)可测试铜、铅、锌、镉、砷、汞6种重金属,但测定六价铬时偏差较大;除六价铬和铜外,阳极溶出伏安法的测试范围较比色法宽,且检出限较低;阳极溶出伏安法可同时测定镉、铅、铜3种金属,具有较好的适用性。
在國內外重金屬鑑測技術的基礎上對環境汙染事故中重金屬(銅、鉛、鋅、砷、汞、鉻、鎘)的兩種主要快速鑑測方法進行瞭研究。研究結果錶明:比色法可測試銅、鉛、鋅、鎘、六價鉻5種重金屬,且精密度與準確度均較好;暘極溶齣伏安法(ASV)可測試銅、鉛、鋅、鎘、砷、汞6種重金屬,但測定六價鉻時偏差較大;除六價鉻和銅外,暘極溶齣伏安法的測試範圍較比色法寬,且檢齣限較低;暘極溶齣伏安法可同時測定鎘、鉛、銅3種金屬,具有較好的適用性。
재국내외중금속감측기술적기출상대배경오염사고중중금속(동、연、자、신、홍、락、력)적량충주요쾌속감측방법진행료연구。연구결과표명:비색법가측시동、연、자、력、륙개락5충중금속,차정밀도여준학도균교호;양겁용출복안법(ASV)가측시동、연、자、력、신、홍6충중금속,단측정륙개락시편차교대;제륙개락화동외,양겁용출복안법적측시범위교비색법관,차검출한교저;양겁용출복안법가동시측정력、연、동3충금속,구유교호적괄용성。
Based on the monitoring technologies of heavy metals in the world,two major rapid methods for monitoring the heavy met-als(Cu,Pb,Zn,As,Hg,Cr and Cd)in environmental pollution accidents were studied in this paper.The results showed that:Col-orimentric method can test the content of Cu,Pb,Zn,Cd and Cr (VI),which reveals a good precision and accuracy;Anodic strip-ping voltammetry(ASV)can test the content of Cu,Pb,Zn,Cd,As and Hg,but has a large discrepancy when applied in testing Cr (VI);ASV has a larger test range and lower detection limit than colorimentric method with exception of Cu and Cr(VI);ASV can test the content of Cd,Pb and Cu simultaneously,which also displays a good applicability.