中国电机工程学报
中國電機工程學報
중국전궤공정학보
ZHONGGUO DIANJI GONGCHENG XUEBAO
2013年
35期
44-49
,共6页
差分吸收光谱法%连续光源%烟气汞%二氧化硫%浓度关系曲线
差分吸收光譜法%連續光源%煙氣汞%二氧化硫%濃度關繫麯線
차분흡수광보법%련속광원%연기홍%이양화류%농도관계곡선
differential optical absorption spectroscopy (DOAS)%continuum source%flue gas mercury%sulfur dioxide%concentration relationship curve
最新的《火电厂大气污染物排放标准》对烟气中SO2和汞的含量做出了严格的规定。该文利用连续光源并基于差分吸收光谱技术分别对单一组分SO2、气态单质汞Hg0及两者的混合气体进行了实验研究。研究表明:对于单一组分SO2的检测,利用傅里叶变换滤法比最小二乘法的反演精度更高;对气态单质汞Hg0的检测,利用特征波长处最大值法的反演精度从整体上稍高于峰面积法;对SO2及Hg0混合组分的检测,先由傅里叶变换反演SO2浓度,再利用浓度关系曲线反演Hg0。结果表明:对于混合气体SO2反演误差不超过5%,而SO2的存在将对Hg0造成更大的干扰,Hg0的反演误差超过20%。
最新的《火電廠大氣汙染物排放標準》對煙氣中SO2和汞的含量做齣瞭嚴格的規定。該文利用連續光源併基于差分吸收光譜技術分彆對單一組分SO2、氣態單質汞Hg0及兩者的混閤氣體進行瞭實驗研究。研究錶明:對于單一組分SO2的檢測,利用傅裏葉變換濾法比最小二乘法的反縯精度更高;對氣態單質汞Hg0的檢測,利用特徵波長處最大值法的反縯精度從整體上稍高于峰麵積法;對SO2及Hg0混閤組分的檢測,先由傅裏葉變換反縯SO2濃度,再利用濃度關繫麯線反縯Hg0。結果錶明:對于混閤氣體SO2反縯誤差不超過5%,而SO2的存在將對Hg0造成更大的榦擾,Hg0的反縯誤差超過20%。
최신적《화전엄대기오염물배방표준》대연기중SO2화홍적함량주출료엄격적규정。해문이용련속광원병기우차분흡수광보기술분별대단일조분SO2、기태단질홍Hg0급량자적혼합기체진행료실험연구。연구표명:대우단일조분SO2적검측,이용부리협변환려법비최소이승법적반연정도경고;대기태단질홍Hg0적검측,이용특정파장처최대치법적반연정도종정체상초고우봉면적법;대SO2급Hg0혼합조분적검측,선유부리협변환반연SO2농도,재이용농도관계곡선반연Hg0。결과표명:대우혼합기체SO2반연오차불초과5%,이SO2적존재장대Hg0조성경대적간우,Hg0적반연오차초과20%。
There are strict rules for SO2 and mercury emissions from stationary sources in the latest emission standard of air pollutants for thermal power plants.. The paper mainly study on the concentration retrieval of the single SO2, single Hg0 and their gas mixture by using of continuum source. Studies have shown that for single SO2, Fourier transform filtering is better than the least squares method;For single Hg0, the maximum value at the characteristics wavelength is superior to the peak area method; For the gas mixture, after retrieving the concentration of SO2 with the Fourier transform filtering, then using the concentration relationship curves to retrieve the Hg0. The results show that, for gas mixture, the retrieval error of SO2 is less than 5%, however, the exist of SO2 will cause a greater interference to Hg0 , the retrieval error of Hg0 is more than 20%.