海洋科学
海洋科學
해양과학
MARINE SCIENCES
2014年
4期
1-6
,共6页
鲁景亮%孙松%张光涛%赵增霞
魯景亮%孫鬆%張光濤%趙增霞
로경량%손송%장광도%조증하
溶解有机物(DOM)%荧光特征%三维荧光光谱技术(EEMs)%胶州湾
溶解有機物(DOM)%熒光特徵%三維熒光光譜技術(EEMs)%膠州灣
용해유궤물(DOM)%형광특정%삼유형광광보기술(EEMs)%효주만
Dissolved organic matter%fluorescent characteristics%excitation-emission matrix spectroscopy%Jiaozhou Bay
利用三维荧光光谱技术(EEMs)结合平行因子分析(PARAFAC)的方法,对2011年8月至9月胶州湾表层海水溶解有机物荧光特征的时间与空间变化进行了研究。PARAFAC 模型共鉴别出四个荧光组分:类蛋白质荧光组分(C1),陆源类腐殖质荧光组分(C2, C4)和海源类腐殖质荧光组分(C3)。类蛋白组分在调查期间的荧光强度最强(0.14±0.06),其余三个组分荧光强度相近(0.07±0.02,0.09±0.02,0.05±0.02)。这四种组分在8月下旬多雨期和9月上旬受径流影响的时期荧光强度较高,在9月下旬雨季影响消退后荧光强度显著降低。研究表明各组分荧光强度总体上与叶绿素 a 浓度显著正相关,与盐度负相关,说明胶州湾夏季FDOM浓度主要受降雨引发的生物活动影响。
利用三維熒光光譜技術(EEMs)結閤平行因子分析(PARAFAC)的方法,對2011年8月至9月膠州灣錶層海水溶解有機物熒光特徵的時間與空間變化進行瞭研究。PARAFAC 模型共鑒彆齣四箇熒光組分:類蛋白質熒光組分(C1),陸源類腐殖質熒光組分(C2, C4)和海源類腐殖質熒光組分(C3)。類蛋白組分在調查期間的熒光彊度最彊(0.14±0.06),其餘三箇組分熒光彊度相近(0.07±0.02,0.09±0.02,0.05±0.02)。這四種組分在8月下旬多雨期和9月上旬受徑流影響的時期熒光彊度較高,在9月下旬雨季影響消退後熒光彊度顯著降低。研究錶明各組分熒光彊度總體上與葉綠素 a 濃度顯著正相關,與鹽度負相關,說明膠州灣夏季FDOM濃度主要受降雨引髮的生物活動影響。
이용삼유형광광보기술(EEMs)결합평행인자분석(PARAFAC)적방법,대2011년8월지9월효주만표층해수용해유궤물형광특정적시간여공간변화진행료연구。PARAFAC 모형공감별출사개형광조분:류단백질형광조분(C1),륙원류부식질형광조분(C2, C4)화해원류부식질형광조분(C3)。류단백조분재조사기간적형광강도최강(0.14±0.06),기여삼개조분형광강도상근(0.07±0.02,0.09±0.02,0.05±0.02)。저사충조분재8월하순다우기화9월상순수경류영향적시기형광강도교고,재9월하순우계영향소퇴후형광강도현저강저。연구표명각조분형광강도총체상여협록소 a 농도현저정상관,여염도부상관,설명효주만하계FDOM농도주요수강우인발적생물활동영향。
Herein, the temporal and spatial variation of fluorescent characteristics of Dissolved Organic Matter in surface seawater in the Jiaozhou Bay, during August and September of 2011 was studied by using Excitation-Emission Matrix Spectrum (EEMs) combined with Parallel Factor Analysis (PARAFAC). Four fluorescent components including protein-like component (C1), terrestrial humic-like component (C2, C4) and marine humic-like component (C3) were identified by PARAFAC. The intensity of protein-like component was the highest (0.14±0.06), and the intensities of the other three components were close (0.07±0.02, 0.09±0.02 and 0.05±0.02) during the investigation. In late August and early Septem-ber, the intensities of four components were high, as influenced by rainfall and surface runoff, and then significantly de-creased in late September after rainfall. This study shows generally positive correlation between intensity of fluorescent components and chlorophyll a while negative correlation between intensity of fluorescent components and salinity. It shows that the concentration of FDOM in the Jiaozhou Bay was mainly influenced by biological activities caused by rainfall.