CAJ | 학술논문

通过γ-辐照含有K2S2O8和BaCl2的二(2-乙基己基)琥珀酸酯磺酸钠(AOT)反相微乳液，将S2O28-通过辐射还原实现了SO24-的原位缓释，从而成功制备出BaSO4纳米纤维单晶，并进一步制得多层次的纳米纤维束结构。在此基础上，通过改变水与表面活性剂物质的量之比(ω值)、改变钡盐阴离子和在微乳液连续相添加芳香化合物等手段来调节水化电子(e-aq)产额，控制微乳液水池中S2O28-的还原和SO24-的缓释速率，成功实现了对BaSO4纳米粒子形貌的调控：随着ω值的增加或剂量率的增加， e-aq产额增加，从而加快了SO24-的释放，不利于BaSO4纳米纤维的生成；采用Ba(NO3)2为钡源时， NO3-能有效地降低e-aq产额和S2O28-的还原速率，因而在较高的剂量率和较高ω值下能得到BaSO4纳米纤维；在微乳液油相中加入甲苯来捕获油相中过量电子(e-oil)，降低e-aq产额，从而在较高的剂量率下得到BaSO4纳米纤维。研究结果表明：通过e-aq产额调控纳米粒子形貌的机理在BaSO4纳米粒子的制备中得到很好体现。
통과γ-복조함유K2S2O8화BaCl2적이(2-을기기기)호박산지광산납(AOT)반상미유액，장S2O28-통과복사환원실현료SO24-적원위완석，종이성공제비출BaSO4납미섬유단정，병진일보제득다층차적납미섬유속결구。재차기출상，통과개변수여표면활성제물질적량지비(ω치)、개변패염음리자화재미유액련속상첨가방향화합물등수단래조절수화전자(e-aq)산액，공제미유액수지중S2O28-적환원화SO24-적완석속솔，성공실현료대BaSO4납미입자형모적조공：수착ω치적증가혹제량솔적증가， e-aq산액증가，종이가쾌료SO24-적석방，불리우BaSO4납미섬유적생성；채용Ba(NO3)2위패원시， NO3-능유효지강저e-aq산액화S2O28-적환원속솔，인이재교고적제량솔화교고ω치하능득도BaSO4납미섬유；재미유액유상중가입갑분래포획유상중과량전자(e-oil)，강저e-aq산액，종이재교고적제량솔하득도BaSO4납미섬유。연구결과표명：통과e-aq산액조공납미입자형모적궤리재BaSO4납미입자적제비중득도흔호체현。
Single-crystal BaSO4 nanofibers and multi-architecture bundles were successful y synthesized in sodium bis(2-ethylhexyl) sulfosuccinate (AOT)-based microemulsions containing K2S2O8 and BaCl2, in which the control ed release of SO24-ions was realized in situ by the radiolytic reduction of S2O28-ions. The molar ratio of water to surfactant (ωvalues), the counterions of Ba2+, and the addition of aromatic compounds into the oil phase of the microemulsions were used to adjust the yield of hydrated electrons (e-aq). This al owed for control ing the reduction of S2O28- ions and the release of SO24- ions, leading to the shape manipulation of BaSO4 nanoparticle. With an increase inωvalues or dose rate, the yield of e-aq increased, which led to a quicker release of SO24-ions, and this did not favor the formation of BaSO4 nanofibers. When BaCl2 was replaced with Ba(NO3)2 the formation of nanofilaments became possible at a higher dose rate and a higherωvalue, because NO3-effectively decreased the yield of e-aq and the rate of S2O28-ion reduction. When toluene was added into the oil phase of the microemulsions, the excess electrons were effectively scavenged in the oil phase, and the concentration of e-aq in the water pool decreased. This favored the formation of nanofibers at higher dose rates. These results showed that the mechanism about morphology control by the yield of e-aq was verified in the syntheses of BaSO4 nanoparticle.