化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
6期
1491-1497
,共7页
梁尤轩%赵斌%姜川%杨俊和
樑尤軒%趙斌%薑川%楊俊和
량우헌%조빈%강천%양준화
垂直碳纳米管阵列%化学气相沉积%动力学%结构调控
垂直碳納米管陣列%化學氣相沉積%動力學%結構調控
수직탄납미관진렬%화학기상침적%동역학%결구조공
vertically-aligned carbon nanotube forest%chemical vapor deposition%kinetics%structure tailoring
垂直碳纳米管(VACNT)阵列由于具有良好的排列、优异的导电导热能力、高比表面积、高纯度等优点而得到广泛应用。本文概述了用于碳纳米管阵列生长的热化学气相沉积(CVD)制备方法的最新进展,重点阐述了CVD法生长碳纳米管阵列的动力学与生长终止机理,指出CVD过程中的催化剂形貌演化是引发碳纳米管阵列生长停止的重要原因。介绍了人们通过生长条件控制与催化剂设计等方法调控碳纳米管阵列结构(包括管壁数、管径和密度)方面取得的进展,指出碳纳米管阵列的大批量制备及结构参数的精确调控是未来发展的重点。
垂直碳納米管(VACNT)陣列由于具有良好的排列、優異的導電導熱能力、高比錶麵積、高純度等優點而得到廣汎應用。本文概述瞭用于碳納米管陣列生長的熱化學氣相沉積(CVD)製備方法的最新進展,重點闡述瞭CVD法生長碳納米管陣列的動力學與生長終止機理,指齣CVD過程中的催化劑形貌縯化是引髮碳納米管陣列生長停止的重要原因。介紹瞭人們通過生長條件控製與催化劑設計等方法調控碳納米管陣列結構(包括管壁數、管徑和密度)方麵取得的進展,指齣碳納米管陣列的大批量製備及結構參數的精確調控是未來髮展的重點。
수직탄납미관(VACNT)진렬유우구유량호적배렬、우이적도전도열능력、고비표면적、고순도등우점이득도엄범응용。본문개술료용우탄납미관진렬생장적열화학기상침적(CVD)제비방법적최신진전,중점천술료CVD법생장탄납미관진렬적동역학여생장종지궤리,지출CVD과정중적최화제형모연화시인발탄납미관진렬생장정지적중요원인。개소료인문통과생장조건공제여최화제설계등방법조공탄납미관진렬결구(포괄관벽수、관경화밀도)방면취득적진전,지출탄납미관진렬적대비량제비급결구삼수적정학조공시미래발전적중점。
Due to good alignment,excellent electrical and thermal conductivity,high surface area, and high carbon purity,vertically-aligned carbon nanotube (VACNT) forests have shown to be advantageous for numerous applications. This paper summarizes recent advances in several chemical vapor deposition (CVD) methods for synthesizing VACNT forests. It focuses on kinetics and termination mechanism of VACNT forest growth by the CVD technique,and catalyst morphology evolution was designated to be the main reason for termination of CNT forest growth. In addition,the progress in structure tailoring of VACNTs (including wall number,diameter and density) through condition control and catalyst designing are also introduced. And,massive growth of VACNT forests and precise control of their structure are regarded as important points to be further studied in the future.