化工进展
化工進展
화공진전
CHEMICAL INDUSTRY AND ENGINEERING PROGRESS
2014年
6期
1357-1364
,共8页
化学链技术%煤转化%氧传递%载氧体%反应器优化
化學鏈技術%煤轉化%氧傳遞%載氧體%反應器優化
화학련기술%매전화%양전체%재양체%반응기우화
chemical-looping technology%coal conversion%oxygen transfer%oxygen carrier%optimal design of reactor
化学链技术为化石能源的清洁高效利用提供了新思路。本文在综述煤化学链燃烧和气化转化工艺现状及特点的基础上,对煤化学链转化的载氧体以及煤-载氧体反应和化学链反应器强化等进行了评价及展望。指出煤化学链转化的研究重点为以下3方面:①载氧体-煤-煤灰-气化剂等反应体系中氧传递过程及反应机理;②载氧体应围绕多活性组分载氧体、耦合催化-载氧-捕C/S多功能复合载氧体和具有特定储氧功能和高稳定性结构载氧体等3方面进行研究;③针对载氧体和煤反应慢的瓶颈,应揭示反应器优化和操作强化的理论基础。
化學鏈技術為化石能源的清潔高效利用提供瞭新思路。本文在綜述煤化學鏈燃燒和氣化轉化工藝現狀及特點的基礎上,對煤化學鏈轉化的載氧體以及煤-載氧體反應和化學鏈反應器彊化等進行瞭評價及展望。指齣煤化學鏈轉化的研究重點為以下3方麵:①載氧體-煤-煤灰-氣化劑等反應體繫中氧傳遞過程及反應機理;②載氧體應圍繞多活性組分載氧體、耦閤催化-載氧-捕C/S多功能複閤載氧體和具有特定儲氧功能和高穩定性結構載氧體等3方麵進行研究;③針對載氧體和煤反應慢的瓶頸,應揭示反應器優化和操作彊化的理論基礎。
화학련기술위화석능원적청길고효이용제공료신사로。본문재종술매화학련연소화기화전화공예현상급특점적기출상,대매화학련전화적재양체이급매-재양체반응화화학련반응기강화등진행료평개급전망。지출매화학련전화적연구중점위이하3방면:①재양체-매-매회-기화제등반응체계중양전체과정급반응궤리;②재양체응위요다활성조분재양체、우합최화-재양-포C/S다공능복합재양체화구유특정저양공능화고은정성결구재양체등3방면진행연구;③침대재양체화매반응만적병경,응게시반응기우화화조작강화적이론기출。
Chemical looping technology paves a new way for the clean utilization of fossil fuel. On the basis of the research status and feature of coal chemical looping combustion/gasification,a summary of oxygen carrier in the chemical looping conversion and the intensification of coal-oxygen carrier reaction and chemical looping reactor was conducted. The researchers should pay much attention to three key points in chemical looping process,including ①further investigation into oxygen transfer and the reaction mechanism of the oxygen carrier-coal-ash-gasifying medium system should be carried out;②We will focus on three kinds of oxygen carriers,oxygen carrier with multi-active component, oxygen carrier coupling with catalysis-oxygen carrying-C/S capture function,and oxygen carrier with oxygen storage;③intensification of reaction and reactor should be processed in the future.