交通科学与工程
交通科學與工程
교통과학여공정
JOURNAL OF CHANGSHA COMMUNICATIONS UNIVERSRTY
2014年
3期
10-14
,共5页
SBS改性沥青%显微相态%网状结构%相容性
SBS改性瀝青%顯微相態%網狀結構%相容性
SBS개성력청%현미상태%망상결구%상용성
SBS modified bitumen%microscopic phase%network structure%compatibility
采用金属制小盛样皿浇注成型制备显微观测样本,在荧光显微镜100倍放大倍数下,观测实验室新制备SBS改性沥青、室温存放2个月的SBS改性沥青及不同厂家提供的成品SBS改性沥青显微相态。观测结果表明:在荧光显微镜下,改性剂的分布形态清晰可见,并且 SBS掺量为4%~5%时,微观上可以达到两相连续的最佳共混状态;随着存放时间的延长,当 SBS掺量大于3%时,改性沥青网状结构逐渐形成,这种网状结构会由于SBS改性剂吸附沥青分子中的油分充分溶胀、发育及分散到沥青中,基质沥青的组分发生重组,从而形成共混体系的空间网状结构。对于不同厂家的成品改性沥青,由于加工工艺和相容性等原因,微观相态存在明显的“聚结”现象,也就是宏观性能表现的“离析”现象。
採用金屬製小盛樣皿澆註成型製備顯微觀測樣本,在熒光顯微鏡100倍放大倍數下,觀測實驗室新製備SBS改性瀝青、室溫存放2箇月的SBS改性瀝青及不同廠傢提供的成品SBS改性瀝青顯微相態。觀測結果錶明:在熒光顯微鏡下,改性劑的分佈形態清晰可見,併且 SBS摻量為4%~5%時,微觀上可以達到兩相連續的最佳共混狀態;隨著存放時間的延長,噹 SBS摻量大于3%時,改性瀝青網狀結構逐漸形成,這種網狀結構會由于SBS改性劑吸附瀝青分子中的油分充分溶脹、髮育及分散到瀝青中,基質瀝青的組分髮生重組,從而形成共混體繫的空間網狀結構。對于不同廠傢的成品改性瀝青,由于加工工藝和相容性等原因,微觀相態存在明顯的“聚結”現象,也就是宏觀性能錶現的“離析”現象。
채용금속제소성양명요주성형제비현미관측양본,재형광현미경100배방대배수하,관측실험실신제비SBS개성력청、실온존방2개월적SBS개성력청급불동엄가제공적성품SBS개성력청현미상태。관측결과표명:재형광현미경하,개성제적분포형태청석가견,병차 SBS참량위4%~5%시,미관상가이체도량상련속적최가공혼상태;수착존방시간적연장,당 SBS참량대우3%시,개성력청망상결구축점형성,저충망상결구회유우SBS개성제흡부력청분자중적유분충분용창、발육급분산도력청중,기질력청적조분발생중조,종이형성공혼체계적공간망상결구。대우불동엄가적성품개성력청,유우가공공예화상용성등원인,미관상태존재명현적“취결”현상,야취시굉관성능표현적“리석”현상。
The microscopic observation sample is prepared by casting molding with a small dish containing softening point ring.Three types of SBS modified bitumen were observed by FM with 100*magnification.These three types of samples are as follows:The first one is produced by our lab,without storing,the second one is produced by our lab and kept at ambient temperature for 2 months,and the third one is from other differ-ent factories.The results indicate that microscopic phase image is very clear,the SBS content is recommended between 4%~5%,which can be achieved on a two-phase con-tinuous microstructure on the best blends.With the increase of the storage period,the network structure of SBS modified bitumen whose SBS content was larger than 3% is gradually formed,and this network structure was contributed to SBS modified bitumen molecules adsorbing oil,which is fully developed into swelling dispersion in the bitu-men,and the component of the bitumen was reorganized,so a new space network struc-ture is formed.For modified bitumen produced by other different factories due to the difference of the process and compatibility,the presence of the microscopic phase ap-pears as “coalescence”phenomenon,and mainly appears as “segregation”on the macro performance.