西华师范大学学报：自然科学版
西華師範大學學報：自然科學版
서화사범대학학보：자연과학판
Journal of China West Normal University:Natural Science Edition
2012年
2期
170-175
,共6页
Gemini表面活性剂%临界胶束浓度%协同效应%临界聚集浓度
Gemini錶麵活性劑%臨界膠束濃度%協同效應%臨界聚集濃度
Gemini표면활성제%림계효속농도%협동효응%림계취집농도
Gemini surfactants%critical micelle concentration%critical aggregation concentrations%synergic effect
评价了一种阳离子型双子表面活性剂溴化-1，4-二[（3-十二烷氧基酰基）吡啶]丁烷（NAE12—4—12）与普通阴离子表面活性剂十二烷基苯磺酸钠、聚丙烯酰胺（PAM）和聚丙烯酸（PAA）的协同作用．实验结果表明NAE12—4—12：SDBS=3：7时，复配效果最好，混合体系的cmc降至0．0031mmol／L，相对于纯NAE12—4—12双子表面活性剂溶液，降低2个数量级；γcmc降低至27．8mN／m，比纯水的张力低44mN／m；该表面活性剂和PAM、PAA的临界缔合浓度cac高于NAE12—4—12的临界胶束浓度cmc，同时混合体系的γcac远低于0．01％PAM及PAA溶液的1值，说明NAE12—4—12与这两种聚合物之间存在较强的相互作用．
評價瞭一種暘離子型雙子錶麵活性劑溴化-1，4-二[（3-十二烷氧基酰基）吡啶]丁烷（NAE12—4—12）與普通陰離子錶麵活性劑十二烷基苯磺痠鈉、聚丙烯酰胺（PAM）和聚丙烯痠（PAA）的協同作用．實驗結果錶明NAE12—4—12：SDBS=3：7時，複配效果最好，混閤體繫的cmc降至0．0031mmol／L，相對于純NAE12—4—12雙子錶麵活性劑溶液，降低2箇數量級；γcmc降低至27．8mN／m，比純水的張力低44mN／m；該錶麵活性劑和PAM、PAA的臨界締閤濃度cac高于NAE12—4—12的臨界膠束濃度cmc，同時混閤體繫的γcac遠低于0．01％PAM及PAA溶液的1值，說明NAE12—4—12與這兩種聚閤物之間存在較彊的相互作用．
평개료일충양리자형쌍자표면활성제추화-1，4-이[（3-십이완양기선기）필정]정완（NAE12—4—12）여보통음리자표면활성제십이완기분광산납、취병희선알（PAM）화취병희산（PAA）적협동작용．실험결과표명NAE12—4—12：SDBS=3：7시，복배효과최호，혼합체계적cmc강지0．0031mmol／L，상대우순NAE12—4—12쌍자표면활성제용액，강저2개수량급；γcmc강저지27．8mN／m，비순수적장력저44mN／m；해표면활성제화PAM、PAA적림계체합농도cac고우NAE12—4—12적림계효속농도cmc，동시혼합체계적γcac원저우0．01％PAM급PAA용액적1치，설명NAE12—4—12여저량충취합물지간존재교강적상호작용．
In this paper, the synergic effect between 1, 4 - bis （3 - （dodecyloxylacyl） pyridinium） tutane） bromide （designated as NAE12 -4 -12） and sodium dodecyl benzene sulfate （SDBS）, polyacrylamide （PAM） polyaerylic acid （PAA） have been studied. The results show that there is good synergic effect between NAE12 -4 - 12 and SDBS at NAE12 -4 - 12 ：SDBS = 3：7. The cmc of the mixture of NAE12 -4 - 12 and SDBS is 0. 0031 mmol/L, which are two orders lower than that of NAE12 -4 - 12 solution free of SDBS. The value of-ycme reduces to 27.8 mN/m, which decreased by 44 mN/m compared with that of pure water. The critical aggregation concentrations of NAE12 -4 - 12 with PAM or PAA are higher than cme of NAE12 -4 - 12, and the γcat of mixture system is much lower than that of 0.01% PAM or PAA, suggesting that there is stronger interaction between NAE12 - 4- 12 and PAM/PPA.
