辽宁石油化工大学学报
遼寧石油化工大學學報
료녕석유화공대학학보
JOURNAL OF LIAONING UNIVERSITY OF PETROLEUM & CHEMICAL TECHNOLOGY
2013年
3期
8-11
,共4页
王九忱%吕焕明%段卫宇%韩新波%于忠%谭秋艳%刘慧玫
王九忱%呂煥明%段衛宇%韓新波%于忠%譚鞦豔%劉慧玫
왕구침%려환명%단위우%한신파%우충%담추염%류혜매
快速检测%甲醇%催化剂%显色剂%萃取
快速檢測%甲醇%催化劑%顯色劑%萃取
쾌속검측%갑순%최화제%현색제%췌취
Rapid test%Methanol%Catalyst%Color-developing%Extraction
提供一种新的快速检测方法,并且配合方法研制出了相应的便携仪器。该方法通过测定萃取液,排除了汽油中烃类和醚类的干扰;通过特殊的复合催化剂A的应用,使得醇类的转化仅到相应醛的程度。以某种特定的酸B为显色剂,排除其他可能存在的醇类的干扰。应用该方法和仪器对10个汽油样品检测(5个车用乙醇汽油,5个车用无铅汽油),以气相色谱法测定值作为真值,考察了该方法的快速性、选择性、可靠性,并比照其他快速法,从测试数据的重复性和准确性方面验证了该方法的优越性。
提供一種新的快速檢測方法,併且配閤方法研製齣瞭相應的便攜儀器。該方法通過測定萃取液,排除瞭汽油中烴類和醚類的榦擾;通過特殊的複閤催化劑A的應用,使得醇類的轉化僅到相應醛的程度。以某種特定的痠B為顯色劑,排除其他可能存在的醇類的榦擾。應用該方法和儀器對10箇汽油樣品檢測(5箇車用乙醇汽油,5箇車用無鉛汽油),以氣相色譜法測定值作為真值,攷察瞭該方法的快速性、選擇性、可靠性,併比照其他快速法,從測試數據的重複性和準確性方麵驗證瞭該方法的優越性。
제공일충신적쾌속검측방법,병차배합방법연제출료상응적편휴의기。해방법통과측정췌취액,배제료기유중경류화미류적간우;통과특수적복합최화제A적응용,사득순류적전화부도상응철적정도。이모충특정적산B위현색제,배제기타가능존재적순류적간우。응용해방법화의기대10개기유양품검측(5개차용을순기유,5개차용무연기유),이기상색보법측정치작위진치,고찰료해방법적쾌속성、선택성、가고성,병비조기타쾌속법,종측시수거적중복성화준학성방면험증료해방법적우월성。
This research affords a new method to test the content of methanol in the gasoline , and a special portable instrument was developed according to this method .The disturbance caused by the existence of hydrocarbons and ethers in gasoline was excluded by extraction ,and the alcohol was selective oxidized to aldehyde over catalyst A ,and the presence of other alcohol can be neglected by selecting suitable color developing agent . The methanol content in 10 different kinds of gasoline samples (including samples of five Ethanol gasolines and of five unleaded gasoline) has been tested by this special instrument .According to the experimental data with GC and this method ,the testing speed ,selectivity and reliability of the method has been investigated , and the results shows that good reproducibility and accuracy of this method has been demonstrated as compared with those of other rapid test methods .