再生资源与循环经济
再生資源與循環經濟
재생자원여순배경제
RENEWABLE RESOURCES AND RECYCLING ECONOMY
2012年
12期
31-34
,共4页
邱玉超%刘聪%苏绍峰%徐东军
邱玉超%劉聰%囌紹峰%徐東軍
구옥초%류총%소소봉%서동군
聚丙烯%聚乙烯%红外光谱%定量检测
聚丙烯%聚乙烯%紅外光譜%定量檢測
취병희%취을희%홍외광보%정량검측
Polypropylene%polyethylene%Infrared Spectrometry%quantitative detection
介绍了热混注塑法制备PP/PE复合体系,并将其用于红外光谱定性和定量分析。分析了聚乙烯PE在聚丙烯PP中的FTIR图谱,确定719cm-1为PE在PP中的特征吸收峰、分析了PE含量对所测谱图和工作曲线的影响。由标准曲线可知,PE的含量与吸收强度具有良好的线性关系,其线性相关系数为0.9992,回收率最低为96.50%,并将其用于再生料PP的检测,其准确性高,对分析PP/PE复合体系再生料具有深远意义.
介紹瞭熱混註塑法製備PP/PE複閤體繫,併將其用于紅外光譜定性和定量分析。分析瞭聚乙烯PE在聚丙烯PP中的FTIR圖譜,確定719cm-1為PE在PP中的特徵吸收峰、分析瞭PE含量對所測譜圖和工作麯線的影響。由標準麯線可知,PE的含量與吸收彊度具有良好的線性關繫,其線性相關繫數為0.9992,迴收率最低為96.50%,併將其用于再生料PP的檢測,其準確性高,對分析PP/PE複閤體繫再生料具有深遠意義.
개소료열혼주소법제비PP/PE복합체계,병장기용우홍외광보정성화정량분석。분석료취을희PE재취병희PP중적FTIR도보,학정719cm-1위PE재PP중적특정흡수봉、분석료PE함량대소측보도화공작곡선적영향。유표준곡선가지,PE적함량여흡수강도구유량호적선성관계,기선성상관계수위0.9992,회수솔최저위96.50%,병장기용우재생료PP적검측,기준학성고,대분석PP/PE복합체계재생료구유심원의의.
This paper introduced preparing PP/PE compound by heating mixing & injection molding, as well as qualitative and quantitative detection by Fourier Transform Infrared Spectroscopy (FTIR). The FTIR of PE was analyzed and 719cm-1 was determined as the characteristic absorption peak for PE. The influence of PE content on infrared spectrogram and standard curve was studied, showing that the content of PE had a good linear relationship with the absorption strength of its characteristic peak. Their correlation coefficient was 0.9992 with a recovery coefficient of 96.50% at least. Finally, the research method was successfully applied to the determination of PE content in recycled PP, which brought profound significance in the analysis of recycled PP/PE compound in the future.