CAJ | 학술논문

采用丙烯酰胺（AM）、丙烯酸（AA）以及单六位取代烯丙胺基β-环糊精（NCD）为原料，合成出了一种水溶性聚合物 AM/ AA/ NCD。采用喹啉、溴乙烷、氟硼酸钠在温和条件下合成了离子液体四氟硼酸1-乙基-喹啉盐（[equin]BF4）。AM/ AA/ NCD 溶液与[ equin]BF4在50℃下回流，发生复合反应，生成 AM/ AA/ NCD-离子液[equin]BF4复合粘土稳定剂。考察了反应条件对聚合反应的影响，确立了最佳合成工艺。通过膨润土线性膨胀实验，确定了复合粘土稳定剂最佳加量为0.6％，防膨率达到81％。采用 X-射线衍射（XRD）考察了复合粘土稳定剂对钠蒙脱土晶层间距的抑制效果，晶层间距从1.89 nm 降低到1.66 nm。压入硬度实验表明，AM/ AA/ NCD-[equin]BF4能有效保持泥页岩岩石强度。
채용병희선알（AM）、병희산（AA）이급단육위취대희병알기β-배호정（NCD）위원료，합성출료일충수용성취합물 AM/ AA/ NCD。채용규람、추을완、불붕산납재온화조건하합성료리자액체사불붕산1-을기-규람염（[equin]BF4）。AM/ AA/ NCD 용액여[ equin]BF4재50℃하회류，발생복합반응，생성 AM/ AA/ NCD-리자액[equin]BF4복합점토은정제。고찰료반응조건대취합반응적영향，학립료최가합성공예。통과팽윤토선성팽창실험，학정료복합점토은정제최가가량위0.6％，방팽솔체도81％。채용 X-사선연사（XRD）고찰료복합점토은정제대납몽탈토정층간거적억제효과，정층간거종1.89 nm 강저도1.66 nm。압입경도실험표명，AM/ AA/ NCD-[equin]BF4능유효보지니혈암암석강도。
A novel copolymer AM/ AA/ NCD was prepared by acrylamide(AM),acrylic acid(AA)and mono-6-(allyl amino)-β-cyclodextrin(NCD). Ionic liquid[equin]BF4 was synthesized using quinolin, bromoethane and sodium fluoroborate(NaBF4 )as starting materials. AM/ AA/ NCD Solution and[equin] BF4 were mixed and refluxed at 50 ℃ for incorporation reaction yielding AM/ AA/ NCD-[ equin]BF4 as clay stabilizer. The structures of AM/ AA/ NCD and[ equin]BF4 were confirmed by Infrared( IR) spectroscopy. The anti-swelling ratio could be 81% when the concentration of clay stabilizer was 0. 6% . The result of X-ray diffractometry(XRD)test showed that the solutions of obtained copolymers could re-markably reduce the interlayer spacing of sodium montmorillonite(from 1. 89 nm to 1. 66 nm)and im-prove the indentation hardness of shale.