东南大学学报(自然科学版)
東南大學學報(自然科學版)
동남대학학보(자연과학판)
JOURNAL OF SOUTHEAST UNIVERSITY
2014年
3期
662-667
,共6页
刘巧玲%孙伟%孙波%孙晓波%贾立群%马正先
劉巧玲%孫偉%孫波%孫曉波%賈立群%馬正先
류교령%손위%손파%손효파%가립군%마정선
水泥基材料%碳纳米管%水性分散体%力学性能%微结构
水泥基材料%碳納米管%水性分散體%力學性能%微結構
수니기재료%탄납미관%수성분산체%역학성능%미결구
cement mortar%carbon nanotubes%water-borne dispersion%mechanical property%mi-crostructure
为了研究碳纳米管及其分散性对水泥砂浆性能的影响,分别采用聚乙烯毗咯烷酮(PVP)和十二烷基磺酸钠(SDBS)两种分散剂制备了不同浓度的碳纳米管水性分散体,探讨了不同碳纳米管水性分散体对水泥砂浆强度及微结构性能的影响.实验结果表明:分散剂对碳纳米管在水中的分散效果影响显著,与SDBS相比,采用PVP为分散剂的碳纳米管水性分散体分散性和稳定性更好;分散性良好的碳纳米管能改善水泥砂浆微结构,提高水泥砂浆的抗压、抗折强度,具有较好的增强效果,当碳纳米管掺量为0.5%时,水泥砂浆28 d抗折强度和抗压强度分别提高了49.4%和40.8%.
為瞭研究碳納米管及其分散性對水泥砂漿性能的影響,分彆採用聚乙烯毗咯烷酮(PVP)和十二烷基磺痠鈉(SDBS)兩種分散劑製備瞭不同濃度的碳納米管水性分散體,探討瞭不同碳納米管水性分散體對水泥砂漿彊度及微結構性能的影響.實驗結果錶明:分散劑對碳納米管在水中的分散效果影響顯著,與SDBS相比,採用PVP為分散劑的碳納米管水性分散體分散性和穩定性更好;分散性良好的碳納米管能改善水泥砂漿微結構,提高水泥砂漿的抗壓、抗摺彊度,具有較好的增彊效果,噹碳納米管摻量為0.5%時,水泥砂漿28 d抗摺彊度和抗壓彊度分彆提高瞭49.4%和40.8%.
위료연구탄납미관급기분산성대수니사장성능적영향,분별채용취을희비각완동(PVP)화십이완기광산납(SDBS)량충분산제제비료불동농도적탄납미관수성분산체,탐토료불동탄납미관수성분산체대수니사장강도급미결구성능적영향.실험결과표명:분산제대탄납미관재수중적분산효과영향현저,여SDBS상비,채용PVP위분산제적탄납미관수성분산체분산성화은정성경호;분산성량호적탄납미관능개선수니사장미결구,제고수니사장적항압、항절강도,구유교호적증강효과,당탄납미관참량위0.5%시,수니사장28 d항절강도화항압강도분별제고료49.4%화40.8%.
In order to study the effects of carbon nanotubes(CNTs)and their dispersion on the per-formance of cement mortars,the aqueous dispersions of carbon nanotubes are prepared using polyvi-nylpyrrolidone (PVP)and sodium dodecyl benzene sulfonate (SDBS)as dispersant,respectively, and their influences on the mechanical and microstructural properties of cement mortars are studied. The experimental results show that dispersant can significantly affect the dispersion of carbon nano-tubes in water.Compared with SDBS as dispersant,the CNTs solution with PVP as dispersant has more uniform dispersion and higher stability.In addition,highly dispersed carbon nanotubes can densify paste microstructure and improve cement mortar's mechanical properties as well.0.5%addi-tion of CNTs can improve the flexural and compressive strength of cement mortars at 28 d by 49 .4%and 40.8%,respectively.